Here we have a very pretty cycle of chemical transmigration. The nitrogen
of the coal plants, stored up in the earth for ages, is restored in the
form of ammonia to the crops of growing beet; the nitrogen is made to
enter into the composition of the latter plant by the chemico-physiological
process going on, and the nitrogenous compounds removed from the plant and
heated to the point of decomposition in presence of the potash (which also
entered into the composition of the plant), give back their nitrogen
partly in the form of a base from which methyl chloride can be obtained.
The latter is then made to methylate a product, aniline, derived indirectly
from coal-tar. The utilisation of the "vinasse" for this purpose was made
known by Camille Vincent of Paris in 1878.
The methylation of aniline can obviously be carried out by the foregoing
process only when beet-sugar residues are available. There is another
method which is more generally used, and which is interesting as bringing
in a distinct branch of industry. The same result can, in fact, be arrived
at by heating dry aniline hydrochloride, _i.e._ the hydrochloric acid salt
of aniline, with methyl alcohol or wood-spirit in strong metallic boilers
under great pressure. This is the process carried on in most factories,
and it involves the use of pure methyl alcohol, a branch of manufacture
which has been called into existence to meet the requirements of the
coal-tar colour maker.[4] This alcohol or wood-spirit is obtained by the
destructive distillation of wood, and is purified by a series of
operations which do not at present concern us. It must be mentioned that
the product of the methylation of aniline, which it is the object of the
manufacturer to obtain, is an oily liquid called dimethylaniline, which,
by virtue of the chemical transformation, is quite different in its
properties to the aniline from which it is derived. By a similar
operation, using ethyl alcohol, or spirit of wine, diethylaniline can be
obtained, and by heating dry aniline hydrochloride with aniline under
similar conditions a crystalline base called diphenylamine is also
prepared.
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