Lithographic stones do not consist merely of carbonate of lime, but
contain also silica, alumina, and some iron; the colour is a useful
indication of quality, those presenting a bluish grey appearance
being most highly prized, while those of a yellow colour are somewhat
inferior. The stone may be split into various thicknesses, and prepared
for use by grinding either one or both surfaces. They are placed face
to face, and the first grinding is completed with coarse sand, for the
second grinding a finer sand is employed between the two surfaces, and
this is succeeded by a grinding with pumice stone and water, the stone
being finally polished with snake stone. The so-called lithographic
chalk, with which the drawing on stone is sometimes executed, is
composed of finest lamp black (merely added for colour), soap, wax,
tallow, and shellac; during the etching, these ingredients undergo a
change, and form with the stone a chemical compound of great stability.
Since the fatty acids of the soap and tallow-namely, oleic and
margaric acid—set free by the nitric acid, combine in the nascent state
with the lime to form oleo-margarate of lime. This adheres tenaciously
to the stone, and the whole picture may, by the application of
turpentine, to all appearances be completely removed from the stone. If
the ink roller be again applied, it will be found that even the finest
details remain intact, and will reappear of their original strength,
the ink only adhering to the oleo-margarate of lime, and not to the
surface of the stone, which owing to the etching is wet with nitrate of
calcium.
This is the theory of lithographic etching and printing, to which it
has only to be added that soap and tallow must always be present in the
inks or chalks used in drawing to produce the combinations referred
to. Wax and shellac are only present as binding material. Transfer
ink, as used in photo-lithography, must be slightly thinned, and this
is best done by means of turpentine, and, if necessary, the occasional
addition of a few drops of olive oil. Should the ink be too stiff, or
be allowed to dry too much upon the transfer paper, the transfer will
probably be faulty, as the ink will only partially leave the paper. If
the ink remains in a soft condition it will be absorbed very readily
by the clean dry litho stone (not etched). Owing to the avidity with
which all grease is absorbed by the stone, it is necessary to keep it
perfectly free from all such contaminations. To keep the stone in a
clean condition while printing it must be etched, kept damp during
working, and, on completion or suspension of work, the surface should
be coated with a thick solution of gum arabic. Before resuming printing
operations, it is of course necessary to remove the gum from the
surface of the stone, which is done with a damp sponge.
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