Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
By the above elegant and economical process, perfectly pure acetic acid of
considerable strength may be produced from even impure alcohol; but it is
impossible in this way to obtain a concentrated acid without a subsequent
operation, because the action of platinum-black on absolute alcohol, or
even on strong alcohol, is so violent that the platinum soon begins to
glow, and inflammation ensues. Unfortunately the revenue laws of this
country, until lately, stood in the way of the adoption of this beautiful
process, unless duty-paid alcohol or methylated spirit be employed; but
there is no statute that prevents an individual employing pure spirit, of
any strength, on the small scale, for private consumption. In Germany, and
in the United States of America, vinegar is manufactured on this plan, and
from the low price of crude alcohol there, it will no doubt prove
ultimately to be the cheapest source of both pure acetic acid and culinary
vinegars.
VI. _Miscellaneous Formulæ_:——
1. An excellent acetic acid, of considerable strength, may be made by
soaking fresh-burnt and perfectly dry charcoal in common vinegar, and then
subjecting it to distillation. The water comes over first, and on
increasing the heat, the acid follows. Vinegar-bottoms and waste vinegar
may be used.
2. By exposing vinegar, or dilute acetic acid, to the air in very cold
weather, or to freezing mixtures, the water separates in the form of ice,
and the strong acetic acid may be obtained by draining it into suitable
glass vessels, observing to do so at a temperature sufficiently low to
keep the water solid. Said to answer well in cold climates.
3. Acetic acid containing 20% of water may be deprived of a good deal of
its superfluous water by standing over dry sulphate of soda. (Liebig.) It
may then be used either with or without distillation.
4. Acetic acid, of ordinary strength, may be concentrated to any degree,
by rectification once, or oftener, from dry acetate of potash or soda,
rejecting the first and last portions. The same acetate may be used
repeatedly. The temperature need not exceed 400°, and must not rise above
570° Fahr.
ACETIC ACID. (B. P.) _Syn._ ACIDUM ACETICUM. Water mixed with 33% of
hydrated acetic acid. Prepared by distilling acetate of soda with
sulphuric acid. Colourless sour liquid. Sp. gr. 1·044.
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