Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Obs._ During the mutual action of the platinum-black and the vapour of
alcohol, the temperature increases, and continues to do so until all the
oxygen contained in the air enclosed in the case is consumed, when the
acetification stops. On opening the case for a short time, to admit of a
fresh supply of air, the operation recommences, thus showing its
dependence on the oxygen of the atmosphere. For this transmutation, 100
grains of alcohol require 71 grains (equal to 200 cubic inches) of oxygen,
or about 1000 cubic inches of atmospheric air. To render the process
continuous and rapid, a fresh supply of air must, therefore, be constantly
provided. This may be effected by either having a loosely covered opening
at the top of the case, and several much smaller ones near its lower part;
or (and preferably) by means of two small glass tubes passing through the
lid or cover, one of which terminates just below the point of insertion,
whilst the other divides into branches which reach to within a short
distance from the bottom, as shown in the _engraving_. In this way a very
slow current of fresh air will always be kept up in the apparatus.
[Illustration]
In practice, we find, that by loosely spreading the platinum-black on
pieces of platinum-gauze, and supporting these on small tripods or bars of
glass or porcelain (or even wood), the watch-glasses and their troublesome
suspension may be dispensed with; as also may be the strip of porous
paper, provided a temperature of not less than 90° Fahr. be maintained in
the case or acetifier, which may easily be done by the application of
artificial heat in the absence of sunshine. On the large scale, a case of
wood with a glass roof, or even a well-seasoned cask or vat may be
employed, in which case the temperature of the apparatus must be kept up
either by means of steam-pipes or flues, or by the supply of warm air. On
the small scale, a hand bell-glass placed on a dish, with a single
watch-glass or piece of platinum-gauze, and a single capsule containing
alcohol, may be used, provided the bell-glass be supported on three very
small wedges, to admit of a supply of air. A modification of this is
sometimes employed, in which the alcohol is supplied, in drops, to the
platinum-black, by means of a long, tubular funnel passing through the
mouth of the bell-glass, and having its lower extremity drawn to a very
fine point, as shown in the _engr._ To ensure success, the platinum-black
should be either fresh-prepared, or recently washed and very gently
heated, before placing it in the acetifier. Spongy platinum, though
ordered by many chemical compilers, does not answer well for this process.
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