Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Any kind of dye found in nature can be made in the laboratory whenever
its composition is understood and usually it can be made cheaper and
purer than it can be extracted from the plant. But to work out a
profitable process for making it synthetically is sometimes a task
requiring high skill, persistent labor and heavy expenditure. One of the
latest and most striking of these achievements of synthetic chemistry is
the manufacture of indigo.
Indigo is one of the oldest and fastest of the dyestuffs. To see that it
is both ancient and lasting look at the unfaded blue cloths that enwrap
an Egyptian mummy. When Caesar conquered our British ancestors he found
them tattooed with woad, the native indigo. But the chief source of
indigo was, as its name implies, India. In 1897 nearly a million acres
in India were growing the indigo plant and the annual value of the crop
was $20,000,000. Then the fall began and by 1914 India was producing
only $300,000 worth! What had happened to destroy this profitable
industry? Some blight or insect? No, it was simply that the Badische
Anilin-und-Soda Fabrik had worked out a practical process for making
artificial indigo.
That indigo on breaking up gave off aniline was discovered as early as
1840. In fact that was how aniline got its name, for when Fritzsche
distilled indigo with caustic soda he called the colorless distillate
"aniline," from the Arabic name for indigo, "anil" or "al-nil," that is,
"the blue-stuff." But how to reverse the process and get indigo from
aniline puzzled chemists for more than forty years until finally it was
solved by Adolf von Baeyer of Munich, who died in 1917 at the age of
eighty-four. He worked on the problem of the constitution of indigo for
fifteen years and discovered several ways of making it. It is possible
to start from benzene, toluene or naphthalene. The first process was the
easiest, but if you will refer to the products of the distillation of
tar you will find that the amount of toluene produced is less than the
naphthalene, which is hard to dispose of. That is, if a dye factory had
worked out a process for making indigo from toluene it would not be
practicable because there was not enough toluene produced to supply the
demand for indigo. So the more complicated napthalene process was
chosen in preference to the others in order to utilize this by-product.
Public-domain text, read in full here on John Shaqi.
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