If u1 and u2 are the velocities with which the positive and negative
ions move, nu1e and nu2e are respectively the quantities of positive
electricity passing in one direction through unit area of the gas per
second, and of negative in the opposite direction, hence
i = nu1e + nu2e.
If X is the electric force acting on the gas, k1 and k2 the velocities
of the positive and negative ions under unit force, u1 = k1X, u2 =
k2X; hence
n = i/(k1 + k2)Xe,
and we have
i [alpha]i²
q = -- + --------------.
ed (k1 + k2)²e²X²
But qed is the saturation current per unit area of the plate; calling
this I, we have
d[alpha]i²
I - i = -------------
e(k1 + k2)²X²
or
i²·d[alpha]
X² = ------------------.
e(I - i)(k1 + k2)²
Hence if we determine corresponding values of X and i we can deduce
the value of [alpha]/e if we also know (k1 + k2). The value of I is
easily determined, as it is the current when X is very large. The
preceding result only applies when i is small compared with I, as it
is only in this case that the values of n and X are uniform throughout
the volume of the gas. Another method which answers the same purpose
is due to Langevin (_Ann. Chim. Phys._, 1903, 28, p. 289); it is as
follows. Let A and B be two parallel planes immersed in a gas, and let
a slab of the gas bounded by the planes a, b parallel to A and B be
ionized by an instantaneous flash of Röntgen rays. If A and B are at
different electric potentials, then all the positive ions produced by
the rays will be attracted by the negative plate and all the negative
ions by the positive, if the electric field were exceedingly large
they would reach these plates before they had time to recombine, so
that each plate would receive N0 ions if the flash of Röntgen rays
produced N0 positive and N0 negative ions. With weaker fields the
number of ions received by the plates will be less as some of them
will recombine before they can reach the plates. We can find the
number of ions which reach the plates in this case in the following
way:--In consequence of the movement of the ions the slab of ionized
gas will broaden out and will consist of three portions, one in which
there are nothing but positive ions,--this is on the side of the
negative plate,--another on the side of the positive plate in which
there are nothing but negative ions, and a portion between these in
which there are both positive and negative ions; it is in this layer
that recombination takes place, and here if n is the number of
positive or negative ions at the time t after the flash of Röntgen
rays,
n = n0/(1 + [alpha]n0t).
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