Encyclopedia of Diet: A Treatise on the Food Question, Vol. 1Christian, Eugene
Science
Encyclopedia of Diet: A Treatise on the Food Question, Vol. 1
Christian, Eugene
Diet; Diet in disease; Food
Impure _acetic acid_ (C₂H₄O₂) is very well known to all under the name
of vinegar. Acetic acid may be obtained by distilling wood. If it could
be manufactured cheaply enough, vinegar made from wood would be fully
as wholesome as the best cider vinegars, but this being an expensive
process of manufacture, the temptation of the food adulterator is to
make the vinegar of sulfuric acid, which is much cheaper than the mild
acetic acid, but much more harmful when taken into the body.
The formic and the acetic acids are examples of a series of organic
acids known as _fatty acids_. Other members of the series are--
Propionic acid C₃H₆O₂
Butyric " C₄H₈O₂
Palmitic " C₁₆H₃₂O₂
Stearic " C₁₈H₃₆O₂
[Sidenote: Process of making soap]
These fatty acids are very important to the food scientist as they
combine with glycerin to form fats. When combined with alkalis under a
certain temperature they form soap. Perhaps some of our older students
may remember the soap kettle on the farm at home, in which lard
cracklings and other fatty fragments of the animal were boiled with lye
or caustic potash to form home-made soap. The chemical action that took
place was a combination of these fatty acids with the caustic potash or
lye. The glycerin was set free and remained in the bottom of the kettle
as soft soap. Reference will be made to these acids again, in Lesson
IV, where the study of fats will be taken up in detail. (See "Fats and
Oils," under Lesson IV, Chemistry of Foods, p. 122).
[Sidenote: Oxalic acid]
There are some other forms of organic acids which do not belong in the
fatty series; that is, they do not contain the same general proportions
of carbon and hydrogen. One of these is oxalic acid (C₂H₂O₄) which is
found in certain plants, such as sorrel, and is an active poison. Oxalic
acid is used in the household for taking iron-rust out of cloth.
[Sidenote: Lactic, malic and tartaric acids]
Lactic acid (C₃H₆O₃) is the acid of sour milk. Malic acid (C₄H₆O₅) is
found in many fruits such as apples, apricots, currants, pears, plums,
prunes, etc. Tartaric acid (C₄H₆O₆) is found principally in grapes.
It is one of the constituent elements in the sediment found in wine
casks, and is the active principle in cream of tartar. The latter is a
potassium salt of tartaric acid.
[Sidenote: Citric acid]
Citric acid (C₆H₈O₇) is one of the most important of the organic acids
from the standpoint of the food chemist. It is the active principle of
citrus-fruits, such as grapefruit, lemons, limes, oranges, etc. Lemons
contain as high as five per cent of this acid. Citric acid is often used
to make lemonade, and if pure citric acid is used, the manufactured
product is equal to the original, except from a sentimental standpoint
of having the genuine. The danger is, as in the case of adulterated
vinegar, that the manufacturer may be tempted to use cheaper mineral
acids instead of citric acid.
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