Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
In order to determine whether the addition of any _acid_ to the water,
would make it more capable of restoring putrid air, I agitated a
quantity of it in a phial containing very strong vinegar; and after that
in _aqua fortis_, only half diluted with water; but by neither of these
processes was the air at all mended, though the agitation was repeated,
at intervals, during a whole day, and it was moreover allowed to stand
in that situation all night.
Since, however, water in these experiments must have imbibed and
retained a certain portion of the noxious effluvia, before they could be
transmitted to the external air, I do not think it improbable but that
the agitation of the sea and large lakes may be of some use for the
purification of the atmosphere, and the putrid matter contained in water
may be imbibed by aquatic plants, or be deposited in some other manner.
Having found, by several experiments above-mentioned that the proper
putrid effluvium is something quite distinct from fixed air, and
finding, by the experiments of Dr. Macbride, that fixed air corrects
putrefaction; it occured to me, that fixed air, and air tainted with
putrefaction, though equally, noxious when separate, might make a
wholesome mixture, the one, correcting the other; and I was confirmed in
this opinion by, I believe, not less than fifty or sixty instances, in
which air, that had been made in the highest degree noxious, by
respiration or putrefaction, was so far sweetened, by a mixture of about
four times as much fixed air, that afterwards mice lived in it
exceedingly well, and in some cases almost as long as in common air. I
found it, indeed, to be more difficult to restore _old_ putrid air by
this means; but I hardly ever failed to do it, when the two kinds of air
had stood a long time together; by which I mean about a fortnight or
three weeks.
The reason why I do not absolutely conclude that the restoration of air
in these cases was the effect of fixed air, is that, when I made a trial
of the mixture, I sometimes agitated the two kinds of air pretty
strongly together, in a trough of water, or at least passed it several
times through water, from one jar to another, that the superfluous fixed
air might be absorbed, not suspecting at that time that the agitation
could have any other effect. But having since found that very violent,
and especially long-continued agitation in water, without any mixture of
fixed air, never failed to render any kind of noxious air in some
measure fit for respiration (and in one particular instance the mere
transferring of the air from one vessel to another through the water,
though for a much longer time than I ever used for the mixtures of air,
was of considerable use for the same purpose) I began to entertain some
doubt of the efficacy of fixed air in this case. In some cases also the
mixture of fixed air had by no means so much effect on the putrid air
as, from the generality of my observations, I should have expected.
Public-domain text, read in full here on John Shaqi.
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