Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendixBattershall, Jesse P. (Jesse Park)
Science
Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendix
Battershall, Jesse P. (Jesse Park)
Food adulteration and inspection; Food adulteration and inspection -- United States
The foregoing method can be applied quantitatively by determining the
strength of the alcohol which will keep in equilibrium a drop of the
fat under examination. Since the difference between 59·2 and 53·7
is 5·5, the difference between the strength of the alcohol used and
53·7, divided by 5·5 (or multiplied by 0·18), will give the proportion
of oleomargarine present. For example, if the globule is held in
equilibrium at 15° in 57 per cent. alcohol, the sample contains about
60 per cent. of oleomargarine, for (57 - 53·7) × 0·18 = 3·3 × 0·18 =
0·594 or, say, 6/10.
The melting-point of butter is below that of most of its fatty
adulterants; as previously stated, it varies from 28° to 37°. The
determination is made either in the ordinary manner by means of a
fine tube, or a little of the chilled sample is attached to a looped
platinum wire, placed near the thermometer-bulb, in water which is
gradually heated until fusion takes place. Blyth gives the following
table of the melting-points of various fats:--
°
Butterine 31·3
Cocoa butter 34·9
Butter (average) 35·8
Beef dripping 43·8
Veal dripping 47·7
Mixed 42·6
Lard, from 42 to 45
Ox fat, from about 48 „ 53
Mutton fat, from about 50 „ 51
Tallow 53·3
Numerous qualitative tests have been proposed by various authorities
for the detection of foreign fats in butter, of which the following are
perhaps sometimes of use. It should be added that the value of these
tests, when applied to mixtures, is limited and very uncertain.
1. A little of the sample is heated in a test-tube: pure butter froths
and acquires a brownish colour; with foreign fats there is but little
foaming, and, although the caseine present darkens, the liquid itself
remains comparatively clear.
2. If a sample containing oleomargarine is melted and the oil burned
in an ordinary lamp-wick, a decided odour of burning tallow will be
produced upon extinguishing the flame. Specimens of real butter,
however, have been found to also emit a tallow-like odour.
3. The melted sample is filtered and treated with boiling ether;
pure butter fat dissolves much more readily than do lard and tallow.
Upon adding methylic alcohol to the solution the latter fats are
precipitated, whereas pure butter will remain in solution.
4. If the filtered fat is distilled with a mixture of alcohol and
sulphuric acid, the distillate will possess the odour of butyric ether
_in a very marked degree_, in case it consists of butter.[27]
5. The strained fat is treated with a solution of carbolic acid (1 part
acid and 10 parts water): genuine butter dissolves to a clear solution;
beef, mutton, and swine fat form two layers, the upper one becoming
turbid upon cooling.
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