The process adopted by M. Daguerre was, to deposit a film of iodine on a highly polished silver plate, by exposing the plate to the vapour of iodine in a dark box. The prepared plate was then placed in the camera, and after an exposure of ten minutes or more, according to the brightness of the day, an impression was made on the iodised silver, but too faint to be visible. To bring out the image thus invisibly impressed, the plate was exposed to the vapour of mercury, in a closed box. The mercury adhered to the parts on which the light had acted, and left the other parts of the plate untouched; and by this means a beautiful representation was produced, in which the deposited mercury represented the lights of the picture, and the polished silver the shadows. The iodised silver remaining on the plate not acted on by light, was washed away by a solution of hyposulphite of soda, and the picture could then be exposed without injury. Nothing can exceed the delicacy of delineation by such a Daguerreotype; for the fine surface of the highly polished silver seems to exhibit the impressions of the smallest objects that emit rays of light. The length of time required to produce an impression was, however, a serious obstacle to the use of the process, as originally invented, for taking portraits. Numerous attempts were consequently made to obtain a more sensitive material. Bromine was tried, in addition to iodine, and with such complete success, that a few seconds were sufficient to effect an impression on the plate, which could be forcibly brought out by the vapour of mercury. It was in 1840 that portraits were first taken by the Daguerreotype process in this country. In the first instance, a concave mirror was employed to concentrate the rays of light on the plate, instead of a lens; and the author has now in his possession a portrait taken in this manner, by "Wolcott's reflecting apparatus." The object of using a concave mirror was to be able to concentrate a greater number of the rays of light than could be done by a lens, and thus to form a brighter image. At the time that portrait was taken, the means had not been discovered of making the mercury adhere to the plate, and a feather would brush it away. Soon afterwards, however, M. Fizeau ingeniously contrived to fix the images on the plate by gilding it. This was done by pouring on to the plate a few drops of a diluted solution of muriate of gold, and holding it horizontally over the flame of a spirit lamp; by which means the gold was deposited and formed a thin, beautiful film of the metal over the surface, and thus not only made the picture more durable, but gave it increased effect.