History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth centuryThorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 1 (of 2): From the earliest time to the middle of the nineteenth century
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
=Stephen Hales= (1677–1761), an ingenious divine—he held the perpetual
curacy of Teddington, and lived practically the greater part of his
life there—distinguished as a physiologist and inventor, occupied
himself in chemical pursuits, and made a number of observations on the
production of gaseous substances. His results were communicated to the
Royal Society and subsequently republished, in a collected form, under
the title of _Statical Essays_. In these experiments he used methods
very similar in principle to those subsequently employed by Priestley.
It is evident from his description of his experiments that he must
have prepared a considerable number of gaseous substances—hydrogen,
carbonic acid, carbonic oxide, sulphur dioxide, marsh gas, etc.—but he
seems to have made no systematic attempt to study their properties,
as he considered that they were simply air, modified or “tinctured”
by the presence of substances which he regarded as more or less
fortuitous. Prior to the time of Black all forms of gaseous substance
were regarded as substantially identical—in fact, as being _air_,
as understood by the Ancients—a simple elementary substance. It was
Black’s study of carbonic acid which first clearly established that
there were essentially distinct varieties of gaseous matter.
CHAPTER VII
PHLOGISTONISM
Even before the appearance of _The Sceptical Chemist_ there was a
growing conviction that the old hypotheses as to the essential nature
of matter were inadequate and misleading. We have seen how the four
“elements” of the Peripatetics had become merged into the _tria
prima_—the “salt,” “sulphur,” and “mercury”—of the Paracelsians. As
the phenomena of chemical action became better known, the latter
iatro-chemists—or, rather, that section of them which recognised that
chemistry had wider aims than to minister merely to medicine—felt that
the conception of the _tria prima_, as understood by Paracelsus and
his followers, was incapable of being generalised into a theory of
chemistry. Becher, while clinging to the conception of three primordial
substances as making up all forms of matter, changed the qualities
hitherto associated with them. According to the new theory, all matter
was composed of a mercurial, a vitreous, and a combustible substance
or principle, in varying proportions, depending upon the nature of the
particular form of matter. When a body was burnt or a metal calcined,
the combustible substance—the _terra pinguis_ of Becher—escaped.
This attempt to connect the phenomena of combustion and calcination
with the general phenomena of chemistry was still further developed
by Stahl, and was eventually extended into a comprehensive theory of
chemistry, which was fairly satisfactory so long as no effort was made
to test its sufficiency by an appeal to the balance.
Public-domain text, read in full here on John Shaqi.
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