History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
By experiments conducted on this principle Kundt and Warburg found that
mercury vapour gave numbers agreeing with the theoretical ratio 1.67.
Now, its vapour density shows that mercury vapour is a monatomic gas;
it actually fulfils the conditions prescribed for a gas which theory
indicates should give the value 1.67. All the energy imparted to its
molecules on heating simply accelerates their translational velocity.
On the other hand, all the gases above named as giving values below
1.67 are diatomic gases; in their case the energy imparted to them
is employed partly in augmenting the translational velocity of the
molecules, and partly in bringing about internal changes within them.
By experiments made in like manner Ramsay and Travers succeeded in
showing that the inert gases of the atmosphere are monatomic.
No attempt can be made here to explain the various methods by which
it has been sought to obtain an estimate of the absolute size of
gaseous molecules or to determine their number in a definite volume. By
observations on their viscosity, rates of diffusion, conductivity for
heat, variations from the law of Boyle, dielectric constants, electric
charges, etc., Maxwell, O. E. Meyer, Loschmidt, Lothar Meyer, Van der
Waals, Mossotti, Planck, Sir J. J. Thomson, and others, have arrived
at estimates of the magnitude and number of molecules in a gas. These
estimates necessarily vary with the hypotheses made in deducing them.
It would serve no useful purpose to give the results, since the figures
convey no impression to the mind of the minuteness of molecules, or
even as to the extraordinary number of them in, say, so small a volume
as one cubic centimetre. As an example, it has been calculated that
there are about 640 trillions of hydrogen molecules in one milligram of
the gas.[3]
[3] O. E. Meyer, _The Kinetic Theory of Gases_, 1899.
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