The tar which remains behind flows through a tube to the cistern. From
the tar separator the gas goes through _scrubbers_ (fig. 12), where the
gas is washed free of ammonia and part of the sulphuretted hydrogen and
carbon dioxide with water. The scrubbers are tower-like vessels filled
with coke or charcoal through which the gas passes from below upwards,
encountering a spray of water. Several scrubbers in series are used, so
that the water constantly becomes richer in ammonia. Mechanical scrubbers
are much used, so-called standard washers; they are rotating, horizontal
cylinders having several chambers filled with staves of wood half dipping
in water. In them the same principle of making the gas meet an opposing
stream of water is employed, so that the last traces of ammonia are
removed from the gas.
The various purifying apparatus through which the gas has to pass cause
considerable resistance to its flow. Escape in various ways would occur
had the gas to overcome it by its own pressure, and too long contact of
the gas with the hot walls of the retorts would be detrimental. Hence an
exhauster is applied to the system which keeps the pressure to the right
proportion in the retorts and drives on the gas.
[Illustration: FIG. 12.—Washer or Scrubber]
After purification in the scrubbers _dry purification_ follows, having
for its object especially removal of compounds of sulphur and cyanogen
and carbon dioxide. To effect this several shallow receptacles are
used, each having a false bottom upon which the purifying material is
spread out. The boxes are so arranged that the gas first passes through
purifying material which is almost saturated and finally through fresh
material, so that the material becomes richer in sulphur and cyanogen
compounds. The _gas purifying material_ formerly used was slaked lime,
and it is still frequently used, but more generally bog iron ore or
artificially prepared mixtures are used consisting mostly of oxide of
iron. The saturated purifying material is regenerated by oxidation on
spreading it out in the air and turning it frequently. After having been
thus treated some ten times the mass contains 50 per cent. sulphur, and
13 to 14 per cent. ferrocyanide.
[Illustration: FIG. 13.—Manufacture of Illuminating Gas. Diagrammatic
view (_after Lueger_) A Retort setting and hydraulic main; B Condensers
and coolers; C Exhauster; D Well; E Water tank; F Tar extractor;
G Scrubber; H Purifier; I Station meter; K Gas holder; L Pressure
regulator.]
The _naphthalene_ in illuminating gas does not separate in the condenser,
and therefore is generally treated in special apparatus by washing the
gas with heavy coal tar.
Public-domain text, read in full here on John Shaqi.
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