Leather: From the Raw Material to the Finished ProductAdcock, K. J.
History
Leather: From the Raw Material to the Finished Product
Adcock, K. J.
Leather
In the pit method of liming, it is essential that the liquors be
frequently plunged, while the hides should be taken out ("hauled"),
piled to drain for a few hours, and put back again ("set"), or
transferred to another pit. Although lime is more soluble in cold
than in warm water, it is found in practice that the process may
be stopped or considerably retarded in very cold weather, and the
activity of the liquors is increased by the application of waste
steam (conveyed through iron pipes from the boiler).
Sulphide of sodium and lime are sometimes made into a thin paste,
which is applied to the hair side of hides and skins with a mop or
fibre brush. The hides are then folded down the back with the flesh
sides out; other hides are similarly treated and placed in a pile.
This saves a great amount of labour in pitting, and, if the paste is
fairly strong, consisting of 2 to 2-1/2 per cent. sulphide, the hair
can be removed after a few hours.
With so many depilatories available, it is not surprising that
several patents have been granted and numerous suggestions made with
the object of trying to improve on the old process of liming. While
there may be some objections to lime, it has a few advantages which
are lacking in other depilatories. These advantages are not perfectly
understood theoretically, but the tanner recognises them in practice.
Hence, there are very few tanneries where lime is not used at all,
and the only progress that seems to have been made in the process of
liming consists in the admixture of sulphide of sodium or arsenic to
hasten the process, reduce the loss of gelatine, and, in the case of
arsenic, to improve the fineness of the grain of skins for boot upper
and glove leathers.
One patented method consisted in forming the calcium hydrate within
the hide by treating it with a 1 per cent. solution of caustic soda
and then with a 1-1/2 per cent. solution of calcium chloride, the
reaction of these two chemicals forming calcium hydrate (lime) and
sodium chloride (salt). This method, however, does not loosen the
hair at all and has to be supplemented by soaking the hides in putrid
water. It is a good method of liming hides or skins dressed in the
hair, as it opens up the fibres without weakening the hair roots and
prepares the hides in a suitable condition for tanning.
Another method consists in mixing a small quantity of soda ash with
the lime, thereby hastening the process by increasing the alkalinity
of the liquor.
Public-domain text, read in full here on John Shaqi.
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