Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of ScienceCorbin, Thomas W.
Science
Marvels of Scientific Invention: An Interesting Account in Non-Technical Language of the Invention of Guns, Torpedoes, Submarine Mines, Up-to-Date Smelting, Freezing, Colour Photography, and Many Other Recent Discoveries of Science
Corbin, Thomas W.
Inventions
Applying a similar process of reasoning to these discoveries, the
conviction grew that the nitrogen of the air was not pure, but that it
had mixed with it a small proportion of some other gas of greater
density. They soon succeeded in isolating this denser gas, to which they
gave the name of argon. Its atomic weight was found, and, wonderful to
relate, it was such that argon fell into a new column to the left of
Group 1, as had been anticipated.
The discovery of argon was announced in 1894. The next year Sir William
Ramsey, investigating a gas which had been discovered locked up in the
interstices of a mineral called clevite, was able to state that it was
helium, the element which had been previously noticed by the
spectroscope in the sun. Like argon, it was found to be extremely
inactive, and its atomic weight turned out to be such that it too fell
into the "Zero Group."
In 1898 Professors Ramsey and Travers found two more gases in the air,
krypton and neon, and a little later still, there was found mixed with
the krypton a further new gas, xenon. All of these had their atomic
weights found, and fell into that new column in the periodic table.
But what has all this got to do with liquid air? The two subjects are
closely related, for it is by liquid-air machines that these rare gases
are now obtained, and it was from liquid air that the last three were
first discovered.
For air, as we well know, is a mixture of gases, and when extreme cold
and pressure are applied these gases liquefy, each behaving according to
its own nature. They do not all liquefy at the same time, nor on being
relieved from the pressure and heated do all evaporate again at the same
temperature. Although they emerge from the liquid-air machine in the
form of a single liquid, it is really a mixture of liquids, each with
its own boiling-point.
In an earlier chapter we saw how petroleum can be separated into its
various constituents, such as petrol, by fractional distillation,
advantage being taken of the difference in the "boiling-point" of the
various "fractions." The boiling-point of a liquid is, of course, the
temperature at which it turns freely into vapour, and just as petroleum
when heated gives off first cymogene, next rhigolene, then petrol,
benzine, kerosene and so on, in the order named, so liquid air, when it
is evaporated, gives off its different constituents in order. Nitrogen,
oxygen, argon, helium, krypton, neon and xenon can all be separated each
from the others in this way, by "fractional distillation." The heat from
the surrounding objects is allowed to get at the liquid, and the gases
are then given off in the order of their boiling-points.
Public-domain text, read in full here on John Shaqi.
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