2. _The Silver Test._—Nitrate of silver yields, with hydrocyanic acid
or cyanide of potassium, a white clotted precipitate, (cyanide of
silver,) insoluble in cold but soluble in boiling nitric acid. If this
precipitate be well dried and heated, cyanogen gas will be given off,
which may be known by its burning with a purplish flame. This test is
very delicate.
3. _The Iron Test._—Of the liquid collected in the receiver
above-mentioned, or the suspected acid liquid, saturated with a few
drops of caustic potass, a portion is to be taken, and to this is to be
added a small quantity of a solution of sulphate of iron. A dirty
brownish or greenish precipitate will fall, consisting of a mixture of
the oxide of iron and prussian blue. On adding a few drops of diluted
sulphuric or hydrochloric acid, and thus dissolving the oxides, the
prussian blue will immediately be made clear if hydrocyanic acid be
present.
4. _The Copper Test._—Sulphate of copper added to prussic acid rendered
slightly alkaline by potass, gives a greenish-white precipitate, which
becomes white by the addition of a few drops of hydrochloric acid to
dissolve the blue precipitated oxide of copper.
5. _The Sulphur Test._—One of the most useful tests for prussic acid,
whether in the fluid or volatile state, is the so-called sulphur or
Liebig’s test. It is best adapted for detecting the acid in a state of
vapor, and to this end a drop of yellow sulphide of ammonium in a
watch-glass is held over the suspected liquid, which may be warmed by
the hand to facilitate the evolution of the acid. In this position the
watch-glass should be allowed to remain for some little time, after
which a drop of solution of perchloride of iron is to be added, which
will give rise to a blood-red color not discharged by corrosive
sublimate.
If the acid is in the liquid form a drop of the prussic acid and the
yellow sulphide may be mixed and heated until they thoroughly combine. A
drop of sulphate of iron is then added as before, but all the sulphide
must be decomposed or a black sulphide of iron will be produced, even
though prussic acid be present, instead of the ordinary blood-red color.
Other substances give a similar reaction with iron; but their color is
discharged by corrosive sublimate.
CHAPTER XXVIII.
DEPRESSANTS.
NEUROTICS PRODUCING MARKED DEPRESSION OF THE HEART’S ACTION.
DIGITALIS—CALABAR BEAN—TOBACCO—HEMLOCK.
DIGITALIS PURPUREA (_Purple Foxglove_).—The seeds, leaves, and root of
this indigenous hedge-plant are poisonous. _Digitalin_ is the principle
which these parts contain. The officinal infusion of digitalis, made
from the dried leaves, is used in doses of ʒij, ℥ss, or more; of
the tincture m. v to m. xl are usually given. On the recommendation of
the late Mr. Jones, of Jersey, half an ounce of the tincture is
sometimes administered in cases of delirium tremens; this dose being
repeated a second or even a third time, in the course of six or eight
hours.
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