The work of liquefying the gases had been taken up by Faraday
during his hours of liberty from other duties. It was probably his
characteristic dislike to “doubtful knowledge” which prompted him to
re-examine a substance which had at one time been regarded as chlorine
in a solid state, but which Davy in 1810 had demonstrated to be a
hydrate of that element. The first work was, as narrated above, to make
a new analysis of the supposed substance. This analysis, duly written
out, was submitted to Sir Humphry, who, without stating precisely what
results he anticipated might follow, suggested heating the hydrate
under pressure in a hermetically sealed glass tube. This Faraday did.
When so heated, the tube filled with a yellow atmosphere, and on
cooling was found to contain two liquids, one limpid and colourless
like water, the other of an oily appearance. Concerning this research
a curious story is told in the life of Davy. Dr. Paris, Davy’s friend
and biographer, happened to visit the laboratory while Faraday was at
work on these tubes. Seeing the oily liquid, he ventured to rally the
young assistant upon his carelessness in employing greasy tubes. Later
in the day, Faraday, on filing off the end of the tube, was startled by
finding the contents suddenly to explode; the oily matter completely
disappearing. He speedily ascertained the cause. The gas, liberated
from combination with water by heat, had under the pressure of its own
evolution liquefied itself, only to re-expand with violence when the
tube was opened. Early the next day Dr. Paris received the following
laconic note:--
DEAR SIR,--
The _oil_ you noticed yesterday turns out to be liquid chlorine.
Yours faithfully,
M. FARADAY.
Later he adopted a compressing syringe to condense the gas, and again
succeeded in liquefying it. Davy, who added a characteristic note to
Faraday’s published paper, immediately applied the same method of
liquefaction by its own pressure to hydrochloric acid gas; and Faraday
reduced a number of other gases by the same means. These researches
were not without danger. In the preliminary experiments an explosion
of one of the tubes drove thirteen fragments of glass into Faraday’s
eye. At the end of the year he drew up a historical statement on the
liquefaction of gases, which was published in the _Quarterly Journal_
for January, 1824. A further statement by him was published in the
_Philosophical Magazine_ for 1836; and in 1844 his further researches
on the liquefaction of gases were published in the _Philosophical
Transactions_.
Public-domain text, read in full here on John Shaqi.
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