Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
_Electrolytically-refined High-conductivity Copper_, which is largely
used for electrical work. The methods by which it is produced ensure
that most of the impurities inimical to high conductivity have been
removed, and the metal is specially free from arsenic, antimony, and
bismuth, as well as from silver and gold. As ordinarily produced
at the electrolytic refinery, it is in the form of cathode plates,
often about 3 feet × 2 feet 6 inches by ¾ inch thick, weighing 150
to 170 lbs. It is then remelted in order to bring it “up to pitch,”
and to give it the necessary mechanical properties, so that it may
be transformed at once into the particular form suitable for the
electrical purposes intended. Such metal often comes into the market in
the form of wire-bar ingots, cakes, or billets, weighing from 70 to 500
lbs. when in bar form, and from 100 to 400 lbs. when in other shapes.
Electrolytic copper is also suitable for the manufacture of alloys.
_Lake Copper._—The copper ores of the Lake Superior district are
particularly pure, and on smelting and furnace-refining yield a
metallic product of great purity which also possesses good mechanical
properties. It is, therefore, particularly suitable for electrical
work. By reason of its satisfactory properties, Lake copper realises
prices which usually rule somewhat higher than those of ordinary
electrolytic copper as quoted on the New York market.
_Best Select Copper._—For the production of copper alloys, such as
best brass, etc., it is essential that the copper should be pure.
The impurities which are present in ordinary tough copper, and which
may be valuable for imparting strength to the material, have a very
harmful effect when present in alloys. In the older Welsh process of
manufacturing copper, a special method was employed for obtaining metal
free from these impurities, especially arsenic and antimony. This was
known as the “best selecting” process.
The principle underlying the method was to conduct the furnace
operations to the stage at which a small quantity of copper, known as
“copper bottoms,” was obtained. The metal so produced has the property
of collecting from the rest of the matte-charge in the furnace, the
gold, the silver, and the great bulk of the other impurities, owing
to its greater solvent power for them. As a result, the greater part
of the matte (“white metal”) was left pure, and from this material
the copper was extracted by continuing the furnace operations in the
usual manner, the resulting product being known as “best select” (B.S.)
copper.
The process was later used principally for the extraction of the gold
in the charge, rather than for obtaining specially pure copper. The
product is essentially a British one, and was largely used for the
manufacture of high quality alloys.
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