Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The appearance, chemical constitution, and physical properties
of mattes vary according to the rate of cooling, and are further
influenced by the nature and amount of the impurities they contain,
and the following statement must be understood to be more or less
general:—Usually low-grade mattes (up to 20 per cent. or so of copper)
are more or less stony in fracture, with a bluish-purple colour; as the
copper contents increase, a reddening of the colour occurs, and also
an increase in the crystalline character and brittleness. Considerable
quantities of moss copper are present in these mattes. Beyond 30 per
cent. of copper, increased softness and brittleness result, with a
darkening towards blue-black in the colour, whilst with the 60 to 70
per cent. mattes the colour becomes in general of a steel-grey hue.
Increase in the copper contents leads to an increase in the density—a
matter which has important applications in connection with the
economical separation of matte from slag, and the slag-losses in
smelting practice.
The specific gravity of the 13 per cent. copper matte is about 4·80.
" 43 " " " 5·18.
" 60 " " " 5·42.
" 80 " " " 5·55.
(_Gibb_ and _Philp_.)
The density in the fluid state, which is the important condition in
smelting, is less than this, and may indeed be somewhat different,
owing to changes in the constitution of the material.
_Copper Silicate_ is formed by the action of copper oxide and silica
on heating. The silicate is decomposed when heated in the presence
of sulphides, resulting in the formation of sulphide of copper and
silicate of the second metal, in consequence of the great affinity of
copper and sulphur. Upon this fact depends the extraction of copper
from various silicate ores, as well as the cleaning of slags high in
copper, which are often added to the sulphide charges in the furnace
with this object. When heated with iron, the silicate is reduced to
metallic copper with the production of silicate of iron; it is also
reduced by carbon in the presence of metallic oxides capable of uniting
with the silica which is liberated.
=The Varieties of Commercial Copper.=—The copper employed industrially
comes into the market in widely differing forms. Different varieties
are named according to the method of manufacture, the uses for which
they are intended, the locality in which they are produced, or by
special trade names. The most important variety is:—
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