Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
The Xylonite Company simply cut the paper into long strips, and introduce
it into the mixed acids by means of forks. The arrangement used by this
Company for holding the mixed acids is a cylindrical vessel divided into a
number of sections, the whole revolving like a turntable, thus allowing
the workman to nitrate successively each lot of paper at a given point.
This Company did not remove the acid from the paper after its immersion,
but plunged it immediately into the water, thus losing a large proportion
of the waste acid. The Celluloid Company, by using the paper in smaller
pieces, and more paper to a pound of acid, and wringing the mixed acid
from the paper before immersion in water, had a better process of
nitration.
Other manufacturers use earthenware vessels, and glass or steel rods,
hooked at one end, having small pieces of rubber hose pulled over the
other end to prevent the hand from slipping. The form of vessel in general
use is that given in Fig. 23. It is large enough to nitrate 1 lb. of
cotton at a time. The hook at one end of the rod enables the workman to
pull the pyroxyline apart, and thus ensures saturation of the fibre. In
the winter the room in which the nitrating is done must be kept at a
temperature of about 70 deg. F. in order to secure equality in the batches.
[Illustration: FIG. 23.--VESSEL FOR NITRATING COTTON OR PAPER.]
The nitrating apparatus of White and Schupphaus (U.S.P., No. 418, 237, 89)
Mr Field considers to be both novel and excellent. The cage (Fig. 24),
with its central perforated cylinder (Fig. 25), is intended to ensure the
rapid and perfect saturation of the tissue paper used for nitrating. The
patentees say that no stirring is required with their apparatus. This,
says Mr Field, might be true when paper is used, or even cotton, when the
temperature of nitration is from 30 deg. to 35 deg. C., but would not be true if
the temperature were raised to 50 deg. to 55 deg. C. The process is as follows:--
The paper is nitrated in the cage (Fig. 25), the bottom of which is formed
by the flanged plate C, fastened to the bottom of the internal cylinder B.
After nitration the cage is carried to a wringer, which forms the basket,
and the acids removed. Finally, the cage is taken to a plunge tank, where
the paper is removed from the cage by simply pulling out the central
perforated cylinder B. Fig. 26 shows the nitrating pot, with its automatic
cover. The plunge tank is shown in plan and section in Figs. 28 and 29.
This apparatus is suitable for the nitration of cotton fibre in bulk at
high or low temperatures. Other methods that have been patented are
Mowbray's (U.S.P., No. 434, 287), in which it is proposed to nitrate paper
in continuous lengths, and Hyatt's (U.S.P., No. 210, 611).
[Illustration: FIG. 24.--CENTRAL PERFORATED CYLINDER.]
[Illustration: FIG. 25.--THE CAGE. WHITE AND SCHUPPHAUS' NITRATING
APPARATUS.]
[Illustration: FIG. 26.--CELLULOID NITRATING POT.]
[Illustration: FIG. 27.--ANOTHER VIEW.]
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