Besides the oxygenated compound, which is formed by the combination of
oxygen with the extractive matters of the plants held in digestion,
there is a production of carbonic acid which saturates the alkaline
lee, and forms a carbonate of lime in the pastel vat. We find this
attached to the sides of the vat in such quantity that the inside of
these vessels becomes incrusted with it to a considerable depth. It is
this product which dyers call the tartar of the vat; it effervesces
with acids, and gives on analysis carbonic acid, lime, and a few
particles of indigo. In the potash vat the solubility of the carbonate
of potash prevents its deposition; but it is very probable that we
have even here a formation of some carbonated products, perhaps in
part formed at the expense of the carbonic acid of the air.
The soluble extractive principle being the only matter which remains
in solution in the bath with the indigo, the lime, &c., we have formed
deposits which, varying both in their volume and in the greater or
less facility with which they are precipitated during the various
periods of fermentation, lead to a more or less considerable waste of
time. If we plunge a piece of woollen tissue into a vat which has been
recently stirred, it will acquire a dark color, and will be found
covered with brown stains which are with difficulty removed. When the
woad or paste vat has been stirred, it need be left two or three hours
only before plunging in the stuff, at least during the early months of
its working, inasmuch as the pastel, being but slightly divided and
attenuated, is readily precipitated; but when, by reason of its
extreme division, in consequence of repeated operations, it is thrown
down with less facility, the dipping should not be performed oftener
than three times in the day.
The Indian vat requires less time than the others; we may even dye
with it an hour after stirring the mixture. The potash, being soluble,
forms no precipitate; while the ligneous fibre of the madder and the
pellicles of the bran become deposited with great facility. We can
also dip with these vats much oftener than with those made by pastel
or woad.
SICKNESS OF THE WARM VAT FOR DYEING WOOL, AND ITS REMEDIES.
We have to thank that excellent practical magazine, “The American
Chemist,” for the following notes on the sicknesses of the warm vat,
by F. W. Kugler, translated from Reimann’s Färberzeintung:—
Public-domain text, read in full here on John Shaqi.
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