In the wool indigo vat, among the principal “sicknesses” is the
blackening of the vat, or “sharpening.” This arises from the presence
of too much lime. When “sharpened,” the liquor, instead of having a
waxy yellow color with a dense blue film on its surface, has no film;
while the liquor is a dark blackish-green, and on being stirred shows
a gray or white scum on its surface, while it emits at the same time a
pungent odor. If the vat is only slightly affected, it is sufficient
to add some bran and madder and to let it stand over night. If it has
not quite recovered by morning, it may be necessary to heat it up,
agitate it, and let it stand for a couple of hours, after which
perhaps the addition of a little lime will be necessary.
If the vat is much sharpened, it is recommended to sink in it a bag of
bran, and leave it over night, when the fermentation will have
restored the vat in a considerable degree; but it will be necessary to
add lime cautiously and by degrees, to bring it to a proper state for
working.
The theory of the souring of the vat is given. Butyric fermentation
takes place under certain circumstances, butyric acid being formed;
and hydrogen is set free, which reduces the indigo. The addition of
lime makes the vat too strongly alkaline, and sets ammonia free, which
gives the pungent odor of the soured (_verschäften_) vat.
Simultaneously the lime with the white indigo forms a difficultly
soluble compound, which settles, and thus interferes with the working
of the vat. The excess of lime must be removed, which is accomplished
by introducing bran, which causes a lactic fermentation; and the
lactic acid neutralizes the excess of lime, and destroys the lime
compound with indigo which had been formed. The lime may be
neutralized by the use of mineral acids, but there is danger in that
case of precipitating the indigo.
A second “sickness” is “becoming too sweet.” The symptoms are,—the
blue veins and surface film disappear on stirring, the foam gives a
rustling sound, the bath assumes a reddish-yellow color, blue goods
placed in the bath lose their color, and the vat has an unpleasant odor.
The vat when “too sweet” needs to be brought to the regular
temperature, and lime to be added cautiously until the vat is brought
to its normal state. It is safer to add an excess of lime and “sour”
the vat, and then bring it back according to the directions under that
head, than to add too little, as less indigo is lost. To use up all
the dye and to dye a light blue, as little lime should be present as
is consistent with the workings of the vat.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account