Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
The air trap is an important though simple part of the pump. Its
shoulder or fall should stand rather higher than the shoulders of the
fall tubes, so that the mercury may run in a thin stream through a
good Torricellian vacuum before it passes down to the fall tubes.
This is easily attained by regulating the main mercury supply at the
pinch cock situated between the tube from the upper reservoir and the
air-trap tube, the other cocks being almost wide open.
It might be thought that the mercury would tend to pick up air in
passing through the rubber connections to the fall tubes, but I have
not found this to be the case in practice. There is, of course, no
difficulty in eliminating the rubber connections between the fall
tubes and the mercury supply from the air trap, but it impresses a
greater rigidity on the structure and, as I say, is not in general
necessary. It must not be forgotten that the mercury always exercises
considerable pressure on the rubber joints, and so there is little
tendency for gas to come out of the rubber.
The thistle funnels at the head of the fall tubes provide a simple and
excellent means of cleaning the fall tubes. For this purpose some
"pure" sulphuric acid which has been boiled with pure ammonium
sulphate is placed in each thistle funnel, and when the fall tube is
dirty the connection to the mercury supply is cut off at the pinch
cock so as to leave the tube between this entry and the head of the
fall tube quite full of mercury, and the sulphuric acid is allowed to
run down the fall tube by raising the stopper. The fall tube should
be allowed to stand full of acid for an hour or so, after which it
will be found to be fairly clean.
Of course the mercury reservoir thus obtains a layer of acid above the
mercury, and as it is better not to run the risk of any acid getting
into the pump except in the fall tubes, the reservoir is best emptied
from the bottom, by a syphon, if a suitable vessel cannot be procured,
so that clean mercury only is withdrawn.
The phosphorus pentoxide tube is best made as shown simply from a bit
of wide tube, with two side connections fused to the rest of the pump.
It is no more trouble to cut the tube and fuse it up again when the
drying material is renewed than to adjust the drying tube to two fixed
stoppers, which is the alternative. The practice here recommended is
rendered possible only by the oxygas blow-pipe with hooked nozzle.
The connection between the pump and tube to be exhausted is made
simply by a short bit of rubber tube immersed in mercury.
The phosphorus pentoxide should be pure, or rather free from
phosphorus and lower oxides; unless this be the case, the vapour
arising from it is apt to soil the mercury in the pump. The
phosphorus pentoxide is purified by distilling with oxygen over
red-hot platinum black; if this cannot be done, the pentoxide should
at least be strongly heated in a tube, in a current of dry air or
oxygen, before it is placed in the drying tube.
Public-domain text, read in full here on John Shaqi.
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