Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=Red Lead.= By the continued oxidation of litharge in reverberatory
furnaces, red lead is produced as a brilliant red pigment with a
specific gravity of 8.7. The pigment particles appear to be of many
sizes, showing a slight tendency to form a compact mass.
=Paranitraniline Red.= Paranitraniline red, a very bright red material
largely used in tinting paints, is prepared by diazotizing
paranitraniline in hydrochloric acid by means of sodium nitrite in the
cold. This compound is rendered insoluble when precipitated directly on
barytes, by acting on it with an alkaline solution of beta naphthol. It
is the most stable and permanent bright red organic pigment which the
paint manufacturer uses. The particles of this pigment appear in various
sizes, due, no doubt, to a massing of the particles in the precipitation
process.
=Chrome Yellow.= The neutral chromate of lead, made from either the
nitrate or acetate of lead and chromate of soda, finds wide use as a
tinting pigment. When precipitated on a white pigment base, various
trade names are given to it. The microscope shows clearly the physical
character of this pigment.
=Zinc Chromate.= This pigment is made either from zinc salts and
bichromate of potash or zinc oxide heated with chrome salts, frequently
in the presence of acid. Like the rest of the chromate pigments, it is a
very slow-drying material, often requiring over a week to set up, unless
considerable drier is added. In spite of the impurities which it
carries, it has shown itself to be one of the most inhibitive pigments
known and has demonstrated its value in even small percentages in paints
for iron and steel. It dries to a hard adherent film that tends to
protect metal from corrosion.
[Illustration: Indian Red]
[Illustration: Metallic Brown]
[Illustration: Basic Lead Chromate (American Vermilion)]
[Illustration: Red Lead]
[Illustration: Paranitraniline]
[Illustration: Chrome Yellow]
=Prussian Blue.= On oxidizing the precipitate resulting from the
interaction of solutions of prussiate of potash and copperas (iron
sulphate), Prussian blue as used in the paint trade is prepared. It has
a specific gravity of 1.9. The pigment shows an amorphous structure, the
particles varying greatly in size.
=Ultramarine Blue.= This bright blue pigment is prepared by burning
silica, china clay, soda ash and sulphur in pots or furnaces. It has a
specific gravity of 2.4. It is of little value as a paint pigment on
account of its sulphur content, which causes darkening when mixed with
lead pigments, and corrosion when applied to iron or steel. The darkness
of the photograph is due to the massing of the pigment particles.
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