Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The drained precipitate is blued (peroxidised) by adding aqua regia
prepared several days previously, and in proportions depending on the
strengths of the two acids. Generally, the aqua regia mixture will be
100 lb. of commercial nitric acid at 30° B. (containing 35·4 lb. of
anhydrous acid) and 62·2 lb. commercial hydrochloric acid at 23° B.
(containing 23·9 lb. of the anhydrous acid); and 40 lb. of this mixture
will suffice for bluing the precipitate resulting from 100 lb. yellow
prussiate. The addition of the aqua regia should take place in a
wooden vessel with constant agitation.
According to another modification, the white precipitate obtained in
the usual way is blued by adding a solution of perchloride of iron,
which may be made from a hematite ore free from clay and carbonate of
lime, or from rouge. The iron oxide, from whatever source, is ground
to a very fine state, and treated with crude hydrochloric acid in
a lead-lined tank, where the mixture remains for several days, and
is constantly stirred. When saturated with iron the clear liquid is
withdrawn for use. To receive it, the white precipitate is rapidly
heated to boiling in a copper vessel, and is then transferred to a
wooden vat, and the iron perchloride solution is stirred in till the
desired tint is produced. The pigment is washed and dried in the
ordinary way, while the supernatant liquor (essentially protochloride
of iron) is poured over old scrap iron and used instead of copperas for
a fresh batch of yellow prussiate.
A solution of perchloride of manganese may be used instead of
perchloride of iron. Inferior qualities of manganese ore can be
employed, and the residues left after treatment with hydrochloric acid
may be washed and dried for sale as purified or peroxidised manganese.
PARIS BLUE.--(1) A synonym for the violet-tinted kind of
Prussian blue.
Public-domain text, read in full here on John Shaqi.
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