Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(2) A series of compounds described below. [_a_] A thorough mixture of
2 parts sulphur and 1 part dry carbonate of soda is gradually heated
in a covered crucible to redness or till fused; a mixture of silicate
of soda and aluminate of soda is then sprinkled in, and the heat is
continued for an hour; the little free sulphur present may be washed
out by water. [_b_] An intimate mixture of 37 parts china-clay, 15
parts sulphate of soda, 22 parts carbonate of soda, 18 parts sulphur,
and 8 parts charcoal, is heated in large crucibles for 24-30 hours;
the mass is re-heated in cast-iron boxes at a moderate temperature
till the desired tint appears, and is finally pulverised, washed, and
dried. [_c_] Gently fuse 1075 oz. crystallised carbonate of soda in its
water of crystallisation; shake in 5 oz. finely-pulverised orpiment,
and, when partly decomposed, as much gelatinous alumina hydrate as
contains 7 oz. anhydrous alumina; add 100 oz. finely-sifted clay, and
221 oz. flowers of sulphur; place the whole in a covered crucible,
and heat gently till the water is driven off, then to redness, so
that the ingredients sinter together without fusing; the mass is then
cooled, finely pulverised, suspended in river-water, and filtered. The
product is heated in a covered dish to dull redness for 1-2 hours, with
occasional stirring. Colourless or brownish patches may occur, and must
be removed.
SAXON BLUE.--Following is a recipe for the preparation of this
pigment, which possesses limited importance.
Dissolve 8 lb. alum and 1 lb. green copperas in 16 gallons of
water. Add separate solutions of pearlash and yellow prussiate till
precipitate ceases to go down. Collect the precipitate when it has
completely settled; wash thoroughly, and dry.
SOLUBLE BLUE.--This term is applied to a variety of Prussian
blue which, while possessing no difference in the matter of chemical
composition, yet has the distinctive feature of being soluble in water,
which the other varieties are not. It no longer enjoys the popularity
it once had as a dye, on account of the severe competition of the
coal-tar colours. Below are some of the most satisfactory formulæ for
its preparation.
(1) Mix 10 lb. of Prussian blue thoroughly in about 10 gallons of cold
water. Then add 5 lb. of yellow prussiate and let the whole mass boil
steadily for several hours. Strain off the liquor and well wash the
precipitate on a filter. Finally dry for use.
(2) Dissolve about 1 cwt. of red prussiate in water and make the
solution hot. Prepare another solution of about 73 lb. of green
copperas in hot water. Mix the two solutions together and boil them for
about a couple of hours. Allow the solid matters to settle out, then
put them on a filter and wash with clean water until a blue coloration
manifests itself in the drainings. The blue residue is then dried as
usual.
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