Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Per cent.
China clay 36·8
Carbonate of soda 36·8
Sulphur 22·0
Coal 4·4
-----
100·0
The proportions for soda and sulphate of soda ultramarine have been
previously given under “sulphate ultramarine.” The ignition is carried
on in a manner similar to that already described. The resultant
green product, owing to its avidity for oxygen, is partially changed
into ultramarine blue by simple contact with the air. It is entirely
converted into the blue variety by roasting with an additional quantity
of sulphur. With care, ultramarine blue may be manufactured in one
operation, by increasing the proportions of soda and sulphur.
(_c_) “_Silica_” _Ultramarine_ is manufactured in the same way as soda
ultramarine, except that, in addition to the other materials, silica to
the extent of 5 or 10 per cent. of the weight of clay is employed. By
this process, ultramarine blue of a slightly reddish tint is obtained
in one operation. The method has, however, one decided drawback, viz.
that the materials employed are rather liable to fuse during ignition.
The faintly reddish hue of “silica” ultramarine becomes more intense
according to the proportion of silica present. “Silica” ultramarine
is said by some to be less readily attacked by acids and by strong
alum solutions than ultramarine prepared by the “sulphate” and “soda”
processes; but Rowland Williams’ experience does not confirm this
statement. He mentions that good artificial ultramarine withstands
the action of weak acids much better than is generally imagined. He
had occasion to test many samples which resisted the action of dilute
acids to a remarkable degree. Most strong acids, of course, decompose
both artificial and native ultramarine, with evolution of sulphuretted
hydrogen. Native ultramarine is, however, less susceptible to the
influence of acids (both strong and dilute) than the artificial
compound. This difference of behaviour is probably due to the fact that
the former contains considerably less sulphur than the latter, and it
is also possible that the constituents of natural ultramarine may be
combined in a somewhat different manner from those of the artificial
product.
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