Gradually two theories arose concerning heat;—one, the Material theory—the theory of Caloric or Phlogiston; the other, the Kinetic theory. Before the beginning of the present century the former theory was generally accepted, and the development of heat was accounted for by asserting that the friction or percussion altered the capacity for heat of the substances acted upon. The heat was squeezed out by the hammer, and the amount of heat in the world was regarded as a certain quantity, which passed from one body to another, and that some substances contained, or could “store away,” more of the material called heat than other substances. Heat was the material of fire—the principle of it, or _materia ignis_; and by these theories Heat, or Caloric, was gradually adopted as a separate material agent—an invisible and subtle matter producing certain phenomena when liberated. So the two theories concerning heat arose at the end of the last century. One, as we have said, is known as the Material, the other as the Kinetic theory. The latter is the theory of motion, so called from the Greek _kinesis_ (motion), or sometimes known as the Dynamic theory of heat, from _dunamis_ (force); or again as Thermo-dynamics. But any possibility of producing a new supply of heat was denied by the materialists. They knew that some bodies possessed a greater capacity for heat than others; but Count Rumford, at Munich, in 1797, astonished an audience by making water boil without any fire! He had observed the great extent to which a cannon became heated while being bored in the gun factory, and influenced by those who maintained the material theory of heat, paid great attention to the evolution of heat. He accordingly endeavoured to produce heat by friction, and by means of horse power he caused a steel borer to work upon a cylinder of metal. The shavings were permitted to drop into a pan of water at 60° Fahrenheit. In an hour after the commencement of the operation the temperature of the water had risen to 107°: in another half-hour the heat of it was up to 142°: and in two hours had measured 170°. Upon this he says: “It is hardly necessary to add that anything which any insulated body or system of bodies can continue to furnish without limitation cannot possibly be a material substance, and it appears to me to be extremely difficult, if not quite impossible, to form any distinct idea of anything capable of being excited and communicated in these experiments except by _motion_.” A few years later Sir Humphrey Davy made his conclusive experiments, and the Material theory of heat received its death-blow.