The second subdivision of this group includes the rocks of a calcareous
nature derived from animal life; that is to say, what are properly
called limestones. They vary in color, structure, and texture almost
indefinitely, and include all possible grades of materials from those
which can be used only as a flux, or for lime burning, through ordinary
building materials to the finest marbles. These rocks are world-wide in
their distribution and limited to no one particular geologic horizon,
but are found in stratified beds among rocks of all ages from the most
ancient to the most recent.
Owing to the fact that their chief constituent, carbonate of lime, is
soluble in ordinary meteoric waters, the rocks have undergone extensive
decomposition, their lime being removed, while their less soluble
constituents or impurities remain to form soil. A single ton of residual
soil represents not infrequently a loss of 100 tons of original rock
matter. As this mass of lime carbonate is removed by solution the
residual soil settles, and as the limestone rocks are more soluble than
the adjacent rock formations limestone formations usually form valley
lands with ridges on either side. Caves are frequently found in such
formations. Furthermore, as the lime is almost all in the form of the
easily soluble lime carbonate it can be very completely removed and the
fertile “limestone soils” are often very deficient in lime and respond
readily to an application of burnt lime, which, not infrequently, is
quarried from the same field. From an agricultural standpoint this group
is of very great interest and importance.
The third subdivision of this group, namely, that of vegetable origin,
includes peat, lignite, coals, etc. Rocks of this group are made up of
more or less fragmental remains of plants. In many of them, as the peats
and lignites, the traces of plant structure are still apparent. In
others, as the anthracite coals, these structures have been wholly
obliterated by metamorphisms.
Plants when decomposing on the surface of the ground give off their
carbon to the atmosphere in the shape of carbon dioxid gas leaving only
the strictly inorganic or mineral matter behind. When, however, they are
protected from the oxidizing influence of the air, by water or by other
plant growth, decomposition is greatly retarded, and a large portion of
the carbonaceous and volatile matters is retained, and by this means
together with pressure from the overlying mass, the material becomes
slowly converted into coal. When this process goes on near the surface
of the earth, and without much pressure, peat or muck is the product.
The fourth subdivision of this group, the phosphatic, forms a class of
rocks limited in extent but of the greatest economic importance. Guano,
coprolites, and phosphatic rocks (the phosphorites) come under this
head.
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