3. _Petermann’s Solution._—One kilogram of citric acid is dissolved
in about two liters of water and 1350 cubic centimeters of ammonia
of 0.925 specific gravity and filled up with water to 5750 cubic
centimeters. The solution then has a specific gravity of 1.09; 300
cubic centimeters of ammonia of 0.925 specific gravity are now added.
=58. Swedish Official Method for Determination of Phosphoric
Acid.=[43]—The Swedish chemists determine phosphoric acid in
fertilizers both by the molybdate and the citrate methods. These
methods carefully conducted according to the directions given below,
give very concordant results. In doubtful cases the former method is
taken as the deciding one, it having proved by long practice to give
very satisfactory results.
_Reagents for the Molybdate Method._—1. _Molybdic Solution._—Prepared
by dissolving 100 grams of finely powdered molybdic acid with heat,
in 400 grams of eight per cent ammonia of 0.967 specific gravity
and pouring the solution into 1,500 grams of nitric acid of one and
two-tenths specific gravity; or else by dissolving 150 grams ammonium
molybdate in one liter of hot water, and pouring the solution into one
liter of nitric acid of 1.2 specific gravity. Prepared in this way,
the molybdic solution will contain, in the former case five per cent,
in the latter case from five to six per cent of molybdic acid, and 100
cubic centimeters of it are required for precipitating one-tenth gram
of phosphorus pentoxid.
2. _Magnesia Mixture._—Prepared from 110 grams of crystallized
magnesium chlorid, 140 grams ammonium chlorid, 700 grams of eight per
cent ammonia of 0.967 specific gravity and 1,300 grams of distilled
water. The mixture is filtered after a few days, if necessary; ten
cubic centimeters of the same are required for precipitating one-tenth
gram of phosphorus pentoxid.
3. _Ten per cent ammonia_ of 0.959 specific gravity.
(a) _Water-Soluble Phosphoric Acid._—1. _Preparation of the Aqueous
Solution._—Of superphosphates and in general fertilizers containing
water-soluble phosphoric acid, a sample of twenty grams is taken,
and water poured over it in a mortar; lumps are crushed lightly, but
completely with the pestle without pulverizing it finer; the whole mass
is then washed into a graduated flask holding one liter, which at once
is filled up to the mark. The volume taken up by the residue insoluble
in water, is left out of consideration in the calculation. The sample
is left standing in the flask (which is occasionally shaken) at the
ordinary temperature of the room for two hours, and the solution is
then filtered.
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