2. _In Bone-meal._—Destroy organic matter in five grams of the sample
by ignition, dissolve the residue in nitric acid, filter from the
insoluble residue, dilute the filtrate to half a liter, take an aliquot
part containing about one-tenth gram phosphorus pentoxid and determine
the phosphoric acid as directed under (a) 2.
3. _In Fish-guano_ (and other fertilizing materials of organic
origin).—The organic matter cannot here be removed by simple ignition,
as in this way a loss of phosphorus may take place; It is therefore
destroyed either in the wet way through nitric acid and potassium
chlorate or in the dry way by fusion with a mixture of potassium
nitrate and sodium carbonate, otherwise the procedure is as in (b) 1.
4. _In Mineral Phosphates._—Determine the phosphoric acid in a solution
obtained by nitric acid; organic matter is destroyed preferably in the
wet way.
5. _In Basic Slag._—Dissolve ten grams of powdered slag by treating it
with 100 cubic centimeters of fuming hydrochloric acid with heat; wash
the solution into a graduated half liter flask, fill to the mark, shake
well, and filter. Determine the phosphoric acid in twenty-five cubic
centimeters of the clear filtrate, according to (a) 2, after having
first, however, evaporated the solution to dryness and then at least
three times evaporated the residue to dryness with concentrated nitric
acid.
=59. Method Employed by the Royal Experiment Station of Holland.=—_A.
Soluble Phosphoric Acid._[44]—The necessary reagents are:
(1) Molybdate solution, made by dissolving 150 grams of ammonium
molybdate in a liter of water and pouring the solution into a liter of
nitric acid of 1.20 specific gravity.
(2) A ten per cent solution of ammonium nitrate.
(3) Strong and dilute ammonia, the latter being between two and
five-tenths and three per cent of 0.988 specific gravity.
(4) Magnesia mixture made by dissolving 110 grams of crystallized
magnesium chlorid, 140 grams of ammonium chlorid, and 700 cubic
centimeters of ammonia of 0.96 specific gravity in water and bringing
the solution to two liters.
(5) Ammoniacal citrate solution, made by dissolving 500 grams of citric
acid in a liter of water, and mixing with four liters of ten per cent
ammonia of 0.96 specific gravity.
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