In green plants the sugars exist chiefly in the sap. In plants cut
green and quickly dried by artificial means the sugars are found
in a solid state. They also exist in the solid state naturally in
certain sacchariferous seeds. Many sugar-bearing plants when allowed
to dry spontaneously lose all or the greater part of their sugar by
fermentation. This is true of sugar cane, sorghum, maize stalks, and
the like. The starches are found deposited chiefly in tubers, roots or
seeds. In the potato the starch is in the tuber, in cassava the tuber
holding the starch is also a root, in maize, rice and other cereals the
starch is in the seeds. The wood-fibers; _viz._, pentosans, lignose,
cellulose, etc., form the framework and support of the plant structure.
Of all these carbohydrate bodies the most important as foods are the
sugars and starches, but a certain degree of digestibility cannot be
denied to other carbohydrate bodies with the possible exception of
pure cellulose. In the following paragraphs the general principles of
determining the sugars and starches will be given and afterwards the
special processes of extracting these bodies from vegetable substances
preparatory to quantitive determination.
=45. Nomenclature.=—In speaking of sugars it has been thought best
to retain for the present the old nomenclature in order to avoid
confusion. The terms dextrose, levulose, sucrose, etc., will therefore
be given their commonly accepted significations.
A more scientific nomenclature has recently been proposed by Fischer,
in which glucose is used as the equivalent of dextrose and fructose
as the proper name for levulose. All sugars are further classified
by Fischer into groups according to the number of carbon atoms found
in the molecule. We have thus trioses, tetroses, pentoses, hexoses,
etc. Such a sugar as sucrose is called hexobiose by reason of the fact
that it appears to be formed of two molecules of hexose sugars. For a
similar reason raffinose would belong to the hexotriose group.[24]
Again, the two great classes of sugars as determined by the structure
of the molecule are termed aldoses and ketoses according to their
relationship to the aldehyd or ketone bodies.
Since sugars may be optically twinned, that is composed of equal
molecules of right and left-handed polarizing matter it may happen that
apparently the same body may deflect the plane of polarization to the
right, to the left, or show perfect neutrality.
Natural sugars, as a rule, are optically active, but synthetic sugars
being optically twinned are apt to be neutral to polarized light.
To designate the original optical properties of the body therefore the
symbols _d_, _l_, and _i_, meaning dextrogyratory, levogyratory, and
inactive, respectively, are prefixed to the name. Thus we may have _d_,
_l_, or _i_ glucose, _d_, _l_, or _i_ fructose, and so on.
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