_Example._
Grams.
Weight of flask, dry and empty 10.0028
Weight of flask after three weeks’ use 10.0030
[Illustration: FIGURE 29. AEREOMETERS, PYKNOMETERS, AND HYDROSTATIC
BALANCE.]
=53. Determination of Density by the Hydrostatic Balance.=—While
the pyknometer is useful in control work and in fixing standards of
comparison, it is not used extensively in practical work. Quicker
methods of determination are desired in such work, and these are
found in the use of other forms of apparatus. A convenient method of
operation consists in determining the weight of a sinker, whose exact
weights in air and in pure water of a definite temperature, have been
previously determined. The instrument devised by Mohr and modified by
Westphal, is based upon that principle, and is extensively used in
practical work. The construction of this apparatus and also that of the
pyknometers and areometers is shown in the illustrations, figures 29
and 30.
[Illustration: FIGURE 30. HYDROSTATIC BALANCE.]
The weight of the sinker is so adjusted that the index of the balance
arm marks zero when the sinker is wholly immersed in pure water at
the standard temperature. The density of a solution of sugar at the
same temperature, is then determined by placing the rider-weights on
the divided arm of the balance, until the index again marks zero. The
density can then be read directly from the position of the weights in
the arm of the balance or calculated therefrom.
=54. The Areometric Method.=—The most rapid method of determining
the density of a solution and the one in most common use, is based
on the distance to which a heavy bulb with a slender graduated stem
will sink therein. An instrument of this kind is called an areometer.
Many forms of this instrument are employed but they all depend on the
same principle and differ only in the manner of graduation. The one of
widest application has the stem graduated in such a manner as to give
directly the specific gravity of the solution in which it is placed.
Others are made with a special graduation giving directly the
percentage of solid matter in the solution. These instruments can be
used only for the special purposes for which they are constructed.
Other forms are provided with an arbitrary graduation, the numbers
of which by appropriate tables can be converted into expressions of
specific gravity or of per cents of dissolved matters. It is not
practicable to give here, a discussion of the principles of the
construction of areometers.[29] The two which are commonly used, are the
baumé hydrometer and the balling or brix spindle.
In the baumé instrument the zero of the scale is fixed at the point
marked by the surface of distilled water at 15°, and the point to which
it sinks in pure monohydrated sulfuric acid at the same temperature is
marked 66, corresponding to a specific gravity of 1.8427.
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