Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
bleaching before nitration there is a loss of spinning quality in the
collodion. The author considers that the new collodion can be used
entirely in place of the ordinary ether-alcohol collodion. With regard
to the properties of the denitrated products they fix all basic colours
without mordant and may be regarded as oxycellulose therefore. The
density of the thread is from 1.5 to 1.55. The thread of 100 deniers
shows a mean breaking strain of 120 grammes with an elasticity of 8-12
p.ct. The cardinal defect of these fibres is their property of
combination with water. Many attempts have been made to confer
water-resistance (18), but without success. Strehlenert has proposed the
addition of formaldehyde (19), but this is without result (20). In
reference to these effects of hydration, the author has made
observations on cotton thread, of which the following table represents
the numerical results:
Breaking Strain
Mean of 20 experiments
Skein of bleached cotton without treatment 825
Skein of bleached cotton without treatment, but wetted 942
Ditto after conversion into hexanitrate, dry 884
The above, wetted 828
The cotton denitrated from above, dry 529
The cotton denitrated as above and wetted 206
The author considers that other patents which have been taken for
spinning nitrocellulose are of little practical account (21) and (22).
The same conclusion also applies to the process of _Langhans_, who
proposes to spin solutions of cellulose in sulphuric acid (23) (24) and
mixtures of sulphuric acid and phosphoric acid.
GROUP 2. _Lustra-cellulose._--Thread prepared by spinning solutions of
cellulose in cuprammonium.
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