Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
This product is made by the Vereinigte Glanzstoff-Fabriken, Aachen,
according to a series of patents under the names of H. Pauly, M. Fremery
and Urban, Consortium mulhousien pour la fabrication de fils brillants,
E. Bronnert, and E. Bronnert and Fremery and Urban (1). The first patent
in this direction was taken by Despeissis in 1890 (2). It appears this
inventor died shortly after taking the patent (3) The matter was later
developed by Pauly (4) especially in overcoming the difficulty of
preparing a solution of sufficient concentration. (It is to be noted
that Pauly's patents rest upon a very slender foundation, being
anticipated in every essential detail by the previous patent of
Despeissis.) For this very great care is required, especially, first,
the condition of low temperature, and, secondly, a regulated proportion
of copper and ammonia to cellulose. The solution takes place more
rapidly if the cellulose has been previously oxidised. Such cellulose
gives an 8 p.ct. solution, and the thread obtained has the character of
an oxycellulose, specially seen in its dyeing properties. The best
results are obtained, it appears, by the preliminary mercerising
treatment and placing the alkali cellulose in contact with copper and
ammonia. (All reagents employed in molecular proportions.) The author
notes that the so-called hydrocellulose (Girard) (5) is almost insoluble
in cuprammonium, as is starch. It is rendered soluble by alkali
treatment.
GROUP 3. _Lustra-cellulose_ prepared by spinning a solution of cellulose
in concentrated chloride of zinc.
This solution has been known for a long time and used for making
filaments for incandescent lamps. The cellulose threads, however, have
very little tenacity. This is no doubt due to the conditions necessary
for forming the solution, the prolonged digestion causing powerful
hydrolysis (1). Neither the process of Wynne and Powell (2) nor that of
Dreaper and Tompkins (3), who have endeavoured to bring the matter to a
practical issue, are calculated to produce a thread taking a place as a
textile. The author has described in his American patent (4) a method of
effecting the solution in the cold, viz. again by first mercerising the
cellulose and washing away the caustic soda. This product dissolves in
the cold and the solution remains unaltered if kept at low temperature.
Experiments are being continued with these modifications of the process,
and the author anticipates successful results. The modifications having
the effect of maintaining the high molecular weight of the cellulose, it
would appear that these investigations confirm the theory of Cross and
Bevan that the tenacity of a film or thread of structureless regenerated
cellulose is directly proportional to the molecular weight of the
cellulose, i.e. to its degree of molecular aggregation (5).
GROUP 4. 'Viscose' silks obtained by spinning solutions of xanthate of
cellulose.
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