Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
In the above section the following publications are referred
to: Chardonnet, 'Compt. rend.,' 1887, 105, 900; and 1889, 108,
962; Silbermann, 'Die Seide,' 1897, v. 2, 143; Herzog,
'Farber-Zeitung,' 1894/5, 49-50; Thiele, ibid. 1897, 133; O.
Schlesinger, 'Papier-Zeitung,' 1895, 1578-81, 1610-12.
_Action of Reagents upon Natural and Artificial Silks._
1. _Potassium hydrate_ in solution of maximum concentration dissolves
the silks proper, (a) China silk on slight warming, (b) Tussah silk
on boiling. The cellulose 'silks' show swelling with discolouration, but
the fibrous character is not destroyed even on boiling.
2. _Potassium hydrate_ 40 p.ct. China silk dissolves completely at
65 deg.-85 deg.; Tussah silk swells considerably at 75 deg. and dissolves at
100 deg.-120 deg.. The cellulose 'silks' are attacked with discolouration; at
140 deg. (boiling-point of the solution) there is progressive solvent
action, but the action is incomplete. The Pauly product is most
resistant.
3. _Zinc chloride_, 40 p.ct. solution. Both the natural silks and
lustra-celluloses are attacked at 100 deg., and on raising the temperature
the further actions are as follows: China silk is completely dissolved
at 110-120 deg.; Tussah silk at 130-135 deg.; the collodion products at
140-145 deg.; the Pauly product was again most resistant, dissolving at
180 deg..
4. _Alkaline cupric oxide_ (glycerin) solution was prepared by
dissolving 10 grs. of the sulphate in 100 c.c. water, adding 5 grs.
glycerin and 10 c.c. of 40 p.ct. KOH. In this solution the China silk
dissolved at the ordinary temperature; Tussah silk and the
lustra-celluloses were not appreciably affected.
5. _Cuprammonium solution_ was prepared by dissolving the precipitated
cupric hydrate in 24 p.ct. ammonia. In this reagent also the China silk
dissolved, and the Tussah silk as well as the lustra-celluloses
underwent no appreciable change.
6. _An ammoniacal solution of nickel oxide_ was prepared by dissolving
the precipitated hydrated oxide in concentrated ammonia. The China silk
was dissolved by this reagent; Tussah silk and the lustra-celluloses
entirely resisted its action.
7. _Fehling's solution_ is a solvent of the natural silks, but is
without action on the lustra-celluloses.
8. _Chromic acid_--20 p.ct. CrO_{3}--solution dissolves both the natural
silks and the lustra-celluloses at the boiling temperature of the
solution.
9. _Millon's reagent_, at the boiling solution, colours the natural
silks violet: the lustra-celluloses give no reaction.
10. _Concentrated nitric acid_ attacks the natural silks powerfully in
the cold; the lustra-celluloses dissolve on heating.
11. _Iodine solution_ (I in KI) colours the China silk a deep brown,
Tussah a pale brown; the celluloses from collodion are coloured at first
brown, then blue. The Pauly product, on the other hand, does not react.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account