Roentgen Rays and Phenomena of the Anode and Cathode.Thompson, Edward P. (Edward Pruden)
History
Roentgen Rays and Phenomena of the Anode and Cathode.
Thompson, Edward P. (Edward Pruden)
X-rays
66. PHOSPHORESCENCE BY CATHODE RAYS.—Substances which generally
phosphoresced by light and cathode rays in the generating bulb, § 55,
also phosphoresced under the influence of the rays in open air,
excepting eosin, gelatin, both phosphorescent in light, were not so in
cathode rays; so also with solutions of fluorescein, magdala red,
sulphate of quinine and chlorophyll. Phosphorescence was less if the
rays first passed through a tube of glass or tinfoil lengthwise. The
phosphorescent light of the phosphides of the alkaline group, uranium
glass, calcspar and some other substances, was so great that the
luminosity of the air was invisible by contrast. The maximum distance at
which phosphorescense was discernable in open air was about 8 cm. The
best phosphorescent screen consisted of paper saturated with
pentadecylparatatolylketone. In order to prepare it, he laid a sheet of
paper upon glass and applied the fused chemical with a brush. As to the
color of the phosphorescence and fluorescence of different substances,
and as to the degree of luminosity outside of the vacuum tube, they were
about the same as reported by Crookes when located within the discharge
tube. §55. Baric and potassic and other double cyanides of platinum,
common flint, glass, chalk and asaron all exhibited the same property as
when exposed to ultra-violet light, that is, fluoresced or
phosphoresced. Sulphide of quinine in the _solid_ state fluoresced, but
not in _solution_. Petroleum spread on a piece of wood fluoresced, and
also fluorescent-hydrocarbons generally.
66_a_. The cathode rays were not easily transmitted by tinfoil or glass,
because the degree of phosphorescence on the screen was greatly reduced
by interposing such sheets. The phosphorescense ceased also by
deflecting internal cathode rays from the window by a magnet. For full
treatment of the phenomena of phosphorescence, see Stokes’ experiments,
described in _Phil. Trans._, 1852, Art. “Change of Refrangibility of
Light.” In brief, Stokes’ theory assumes that such substances have the
power of reducing the refrangibility. Example: Ultra-violet light,
highly refractive, is changed to yellowish green, less refrangible, by
reflection from uranium glass.
67. THE ALUMINUM WINDOW, A DIFFUSER OF CATHODE RAYS. § 63_b_. The
conclusion arrived at by mounting the phosphorescent screen in different
positions and at different angles as well as by observance of the
gaseous luminosity, was that the aluminum window scattered the
rectilinear parallel cathode rays in all directions, § 57.
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