Scientific American Supplement, No. 1157, March 5, 1898Various
Science
Scientific American Supplement, No. 1157, March 5, 1898
Various
Science -- Periodicals
Many other recipes have been advocated at different times to make a
product resembling caoutchouc out of linseed oil in combination with
other substances, but all have failed to give satisfaction, save as
adulterants to pure rubber.
Among the best compounds in use in rubber factories at present is one
made by boiling linseed oil to the consistency of thick glue.
Unbleached shellac and a small quantity of lampblack is then stirred
in. The mass is boiled and stirred until thoroughly mixed. It is then
placed in flat vessels exposed to the air to congeal.
While still warm the blocks formed in the flat vessels are passed
between rollers to mix it as closely as possible. This compound was
asserted by its inventor to be a perfect substitute for caoutchouc. It
was also stated that it could be vulcanized. This was found to be an
error, however. The compound, upon the addition of from 15 to 25 per
cent. of pure rubber, may be vulcanized and used as a substitute for
vulcanized rubber.
Compounds of coal tar, asphalt, etc., with caoutchouc have been
frequently tested, but they can only be used for very inferior goods.
The need for a substitute for gutta percha is even more acute than for
artificial India rubber. A compound used in its stead for many
purposes is known as French gutta percha. This possesses nearly all
the properties of gutta percha. It may be frequently used for the same
purposes and has the advantage of not cracking when exposed to the
air.
Its inventors claimed that it was a perfect substitute for India
rubber and gutta percha, fully as elastic and tough and not
susceptible to injury from great pressure or high temperature.
The composition of this ambitious substance is as follows: One part,
by weight, of equal parts of wood tar oil and coal tar oil, or of the
latter alone, is heated for several hours at a temperature of from 252
to 270 degrees Fahrenheit, with two parts, by weight, of hemp oil,
until the mass can be drawn into threads. Then one-half part, by
weight, of linseed oil, thickened by boiling, is added. To each 100
parts of the compound one-twentieth to one-tenth part of ozokerite and
the same quantity of spermaceti are added.
The entire mixture is then again heated to 252 degrees Fahrenheit and
one-fifteenth to one-twelfth part of sulphur is added. The substance
thus obtained upon cooling is worked up in a similar manner to natural
India rubber. It has not been successfully used, however, without the
addition of a quantity of pure rubber to give it the requisite
elasticity.
A substitute for gutta percha is obtained by boiling the bark of the
birch tree, especially the outer part, in water over an open fire.
This produces a black fluid mass, which quickly becomes solid and
compact upon exposure to air.
Public-domain text, read in full here on John Shaqi.
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