Scientific American Supplement, No. 286, June 25, 1881Various
Science
Scientific American Supplement, No. 286, June 25, 1881
Various
Science -- Periodicals
In saying that when cyanogen combines with chlorine there is naturally
no condensation, Mr. Greene has no idea that this natural law is fatal
to his artificial law of Avogadro and Ampere; "for," continues he, "the
theory is fulfilled by the actual reaction." It is not. The theory
requires two vols. of cyanogen and two vols. of chlorine, that is, the
unit of numbers, to enter into reaction and to produce two vols. of
the compound. But they produce four vols., and the non-condensation is
therefore in opposition to the theory. It is true beyond doubt that the
molecular weight of cyanogen chloride is contained in two volumes, in
spite of the hypothesis, not on the ground of it; two vols. + two vols.,
producing four vols.; two vols. could, theoretically, contain only half
the unit of numbers, and there seems to be no escape from the following
general conclusions:
1. Two vols. of CNCl, representing the unit of numbers, the constituent
weights, C=12, N=14, Cl=35.5, must each, likewise, represent the same
number; the molecular weight is, therefore, contained in one vol. of N
or Cl, but in two of CNCl and equal numbers are not contained in equal
volumes.
2. The weights N=14, Cl=35.5 occupy in the free state one volume, but
in the combination, CNCl, two volumes; their specific gravity is,
therefore, by chemical action reduced to one half. The fact thus
elicited of the variability and variation of the specific gravity is of
fundamental importance and involves the irrelevancy of the mathematical
demonstration of the hypothesis. In this demonstration the specific
gravity is assumed to be constant, and this assumption not holding good,
and the number of molecules in unit of volume being reduced to one half
when the specific gravity is reduced to the same extent by chemical
action, it is obvious that the mathematical proof must fail. Mr. Greene
states that I have proceeded to demolish C. Clerk Maxwell's conclusion
from mathematical reasoning. This is incorrect; I have found no fault
with the conclusion of the celebrated mathematician, and consider his
reasoning unimpeachable. I am also of opinion that he is entitled to
great credit and respect for the prominent part he has taken in the
development of the kinetic theory, and further think that it was for
the chemists to produce the fact of the variability of the specific
gravities, which they would probably not have failed to do but for the
prevalence of Avogadro's hypothesis, which is virtually the assertion of
the constancy of the specific gravities.
3. The unit of numbers being represented by Cl=35.5, it is likewise
represented by H=1, and as the product of the union of the two elements
is HCl, 36.5 = two vols., combination takes place by addition and not by
substitution; consequently are
4. The elementary molecules not compounds of atoms? And the distinction
between atoms and molecules is an artificial one, not justified by the
natural facts.
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