Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
In regard to the danger of using the lighter petroleum oils, the
following, under the head of "Naphtha and Benzine under False Names," is
taken from Prof. C. F. Chandler's article on "Petroleum" in Johnson's
Cyclopedia. He says: "Processes have been patented, and venders have
sold rights throughout the country, for patented and secret processes
for rendering gasoline, naphtha, and benzine non-explosive. Thus
treated, these explosive oils, just as explosive as before the
treatment, are sold throughout the country under trade names. These
processes are not only totally ineffective, but they are ridiculous.
Roots, gums, barks, and salts are turned indiscriminately into the
benzine, to leave it just as explosive as before. No wonder we have
kerosene accidents, with agents scattered through the country selling
county rights and teaching retail dealers how to make these murderous
'non-explosive' oils. The experiments these venders make to deceive
their dupes are very convincing. None of the petroleum products
are explosive _per se_, nor are their vapors explosive under all
circumstances when mixed with air. A certain ratio of air to vapor is
necessary to make an explosive mixture. Equal volumes of vapor and air
will not explode; three parts of air and one of vapor gives a vigorous
puff when ignited in a vessel; five volumes of air to one of vapor gives
a loud report. The maximum degree of violence results from the explosion
of eight or nine parts of air mixed with vapor. It requires considerable
skill to make at will an explosive mixture with air and naphtha, and it
is consequently very easy for the vender not to make one. In most cases
the proportion of vapor is too great, and on bringing a flame in contact
with the mixture it burns quietly. The vender, to make his oil appear
non-explosive, unscrews the wick-tube and applies a match, when the
vapor in the lamp quietly takes fire and burns without explosion. Or he
pours some of the 'safety oil' into a saucer and lights it. There is no
explosion, and ignorant persons, biased by the saving of a few cents
per gallon, purchase the most dangerous oils in the market. It is not
possible to make gasoline, naphtha, or benzine safe by any addition that
can be made to it. Nor is any oil safe that can be set on fire at the
ordinary temperature of the air. Nothing but the most stringent laws,
making it a State prison offense to mix naphtha and illuminating oil, or
to sell any product of petroleum as an illuminating oil or fluid to be
used in lamps, or to be burned, except in air gas machines, that will
evolve an inflammable vapor below 100 degrees, or better, 120 degrees
Fahrenheit, will be effectual in remedying the evil. In case of an
accident from the sale of oil below the standard, the seller should be
compelled to pay all damages to property, and, if a life is sacrificed,
should be punished for manslaughter. It should be made extremely
hazardous to sell such oils." Prof Chandler is professor of analytical
Public-domain text, read in full here on John Shaqi.
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