Scientific American Supplement, No. 362, December 9, 1882Various
Science
Scientific American Supplement, No. 362, December 9, 1882
Various
Science -- Periodicals
It has been claimed that the evolved products enumerated above are the
results of the primary decomposition of organic matter, and never of
further changes in the residual products; i.e., that in the breaking-up
of organic tissue, variable quantities of coal, anthracite, petroleum,
marsh gas, etc., are formed, but that these are never derived, the one
from the other. This opinion is, however, certainly erroneous, and the
formation of any or all the evolved products may take place throughout
the entire progress of the decomposition. Marsh gas and carbonic acid
are seen escaping from the surface of pools where recent vegetable
matter is submerged, and they are also eliminated in the further
decomposition of peat, lignite, coal, and carbonaceous shale. Fire damp
and choke-damp, common names for the gases mentioned above, are produced
in large quantities in the mines where Tertiary or Cretaceous lignites,
or Carboniferous coals or anthracites are mined. It has been said that
these gases are simply locked up in the interstices of the carbonaceous
matter and are liberated in its excavation; but all who have worked coal
mines know that such accumulations are not sufficient to supply the
enormous and continuous flow which comes from all parts of the mass
penetrated. We have ample proof, moreover, that coal, when exposed to
the air, undergoes a kind of distillation, in which the evolution
of carbonic acid and hydrocarbon gases is a necessary and prominent
feature.
The gas makers know that if their coal is permitted to lie for months or
years after being mined, it suffers serious deterioration, yielding a
less and less quantity of illuminating gas with the lapse of time.
So coking coals are rendered dry, non-caking, and valueless for this
purpose by long exposure.
Carbureted hydrogen, olefiant gas, etc., are constant associates of the
petroleum of springs or wells, and this escape of gas and oil has been
going on in some localities, without apparent diminution, for two or
three thousand years. We can only account for the persistence of this
flow by supposing that it is maintained by the gradual distillation of
the carbonaceous masses with which such evolutions of gas or of liquid
hydro-carbons are always connected. If it were true that carbureted
hydrogen and petroleum are produced only from the primary decomposition
of organic tissue, it would be inevitable that at least the elastic
gases would have escaped long since.
Oil wells which have been nominally exhausted--that is, from which the
accumulations of centuries in rock reservoirs have been pumped--and
therefore have been abandoned, have in all cases been found to be slowly
replenished by a current and constant secretion, apparently the product
of an unceasing distillation.
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