Scientific American Supplement, No. 392, July 7, 1883Various
Science
Scientific American Supplement, No. 392, July 7, 1883
Various
Science -- Periodicals
The destruction by oxidizing agents of the effect produced by light was
then experimentally demonstrated, and photographs of the spectrum showed
that this effect was increased by the action of light itself. Thus, when
immersing a plate sensitive to all radiations, visible and invisible,
in a very dilute solution of nitric acid, bichromate of potash, or
hydroxyl, it was shown that if the plate were exposed to light, first
the parts acted upon by the red rays were reduced before the parts not
acted upon at all by the spectrum, thus conclusively proving that light
itself helped forward the oxidation or so-called solarization of the
image. It thus became a struggle, under ordinary circumstances, between
the reducing action on the normal salt and the oxidizing action on the
altered salt as to which should gain the mastery. If the reducing action
of any particular ray were the most active, then a negative image
resulted, whereas if the oxidizing action were in the ascendant, a
positive image resulted. Thus, in determining the action of light on
a particular salt, this antagonism had to be taken into account, and
exposure made with such precautions that no oxidizing action could
occur, as would be the case if an inorganic sensitizer, such as sulphite
of soda, were used.
The reversal of the image by soluble haloid salts, such as bromide of
potassium, was then dwelt upon with experimental demonstration. It was
shown that the merest trace of soluble haloid would reverse an image
by the extraction of bromine from it, and the fact that the most
refrangible part of the spectrum was principally efficacious in
completing this action showed how necessary it was to avoid falling
into error when analyzing photographic action by the spectroscope. A
reference was next made to gelatine plates, in which, owing to their
preparation, reversal through the above cause was most likely to take
place, and a plate soaked in sulphite of soda and exposed in the camera
for a couple of minutes--a time largely in excess of that necessary to
give a reversal under ordinary circumstances--proved the efficacy of
the oxygen absorber, the image remaining in its normal condition after
development.
The lecturer closed his remarks by showing the different molecular
states of iodide, bromide, and chloride of silver, as produced by
different modes of preparation. The color of the film by transmitted
light in every case indicated the effect which was likely to be produced
on them, and the photographed spectrum in each of them showed the
remarkable differences that were found. The points raised by Captain
Abney at different times are well worthy the study of scientific
photographers, since strict attention to the modes of exposure to the
spectrum, to the instruments employed, and to the source of light used
can alone insure accuracy in comparative experiments.--_Br. Jour. of
Photo_.
* * * * *
SALT AND LIME.
Public-domain text, read in full here on John Shaqi.
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