Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
Theoretically considered, it is proper that the last trace of silver
nitrate should be removed; but those who are engaged in the daily
practice of commercial work do not insist upon the strict observance
of such a rule in all cases. An especial exception is permitted and
advocated when dealing with prints from weak or underexposed negatives,
this class being found to yield richer tones by not washing any of the
free silver out.
The plan of soaking prints in a solution of sodium acetate was
originally recommended, in lieu of washing, by a member of this
Association, Mr. A. L. Henderson, as long ago as 1861, the following
being an outline of the method suggested by him: Slightly overprinted
proofs were soaked in a bath composed of
Sodium acetate 240 grains.
Water 10 ounces.
The unwashed proofs were moved about in this solution at least ten
minutes, in order to convert all the free silver nitrate into acetate
of silver. After slight rinsing in clean water the proofs were toned
with
Gold terchloride 4 grains.
Sodium acetate 240 "
Water 10 ounces.
Among the advantages claimed was an entire absence from mealiness, a
defect, you will remember, we now avoid by the adoption of ammoniacal
fuming.
Guide-books to the practice of printing usually recommended three
rapid washings; the decomposing action thus set up by the quantity of
free silver remaining in the paper materially quickens the speed of
toning. To prevent a too rapid deposition of gold some printers prefer
adding a small quantity of common salt to the toning bath, which turns
the prints sufficiently red and acts in some respects equal to an
intermediary bath.
Preserved papers--containing, as they generally do, a certain
proportion of free acid--are liable to give some trouble in toning,
owing to the retarding action of the acid present. When this occurs, it
is in a great measure overcome by the use of an intermediate bath of
an alkaline character and sufficient strength to neutralize the acid.
Either the carbonates of ammonia or soda are found useful for this
purpose, and I cannot do better than quote the one mentioned by Mr.
Frederick York, which, it will be remembered, is composed of
Washing soda 1 ounce.
Water 1 gallon.
Prints treated in the manner described are ready for toning by the
alkaline method to be dealt with later on.
This brings us to the consideration of toning baths generally. The
properties of toning baths vary somewhat according to the mode of
preparation. The term "toning," as we understand it, implies a
certain change of color brought about by chemical means, such as the
deposition of a stable metal upon one that is easily affected by the
atmosphere--electrolysis, in fact.
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