Scientific American Supplement, No. 470, January 3, 1885 — John Shaqi
Scientific American Supplement, No. 470, January 3, 1885Various
Science
Scientific American Supplement, No. 470, January 3, 1885
Various
Science -- Periodicals
its use as reagent. Adulteration of solid or semi-liquid fats, especially
lard, butter, and tallow, with vegetable oils are readily detected by this
method, since the latter yield on examination a high percentage of iodine.
Animal fats, absorb comparatively less halogen than vegetable fats, and
the power to combine with iodine increases with the transition from the
solid to the liquid state, and attains its maximum with vegetable
oils--the method being adapted to the examination of fat mixtures
containing glycerides and free saturated fatty acids, provided that
substances which under similar conditions combine with iodine are absent.
These conditions are fulfilled with regard to the examination of animal
fats and soap. Ethereal oils are also acted upon by iodine; the reaction
proceeds similar to that observed in ordinary fat mixtures. Alcoholic
mercury iodo-chloride can probably be used with success in synthetical
chemistry, as it allows determination of the free affinities of the
molecule and conversion of unsaturated compounds into saturated
chlorine-iodo addition products.--_Rundschau._
* * * * *
NOTES ON NITRIFICATION.[2]
[Footnote 2: A paper by R. Warington, read before the Chemical Section of
the British Association at Montreal.]
By R. WARINGTON.
In the following brief notes I propose to consider in the first place the
present position of the theory of nitrification, and next to give a short
account of the results of some recent experiments conducted in the
Rothamsted Laboratory.
_The Theory of Nitrification._--The production of nitrates in soils, and
in waters contaminated with sewage, are facts thoroughly familiar to
chemists. It is also well known that ammonia, and various nitrogenous
organic matters, are the materials from which the nitric acid is produced.
Till the commencement of 1877 it was generally supposed that this
formation of nitrates from ammonia or nitrogenous organic matter was the
result of simple oxidation by the atmosphere. In the case of soil it was
imagined that the action of the atmosphere was intensified by the
condensation of oxygen in the pores of the soil; in the case of waters no
such assumption was possible. This theory was most unsatisfactory, as
neither solutions of pure ammonia, nor of any of its salts, could be
nitrified in the laboratory by simple exposure to air. The assumed
condensation of oxygen in the pores of the soil also proved to be a
fiction as soon as it was put by Schloesing to the test of experiment.
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