Scientific American Supplement, No. 497, July 11, 1885Various
Science
Scientific American Supplement, No. 497, July 11, 1885
Various
Science -- Periodicals
I first take clam shells and, after cleaning, place them in a solution
composed of about one part of commercial nitric acid and three parts of
water, in which the shells are allowed to remain about twenty minutes.
The shells are then to be well rinsed in water, placed in a crucible,
and heated to a red heat for about four hours. They are then removed and
placed, while still red-hot, in a saturated solution of sea salt, from
which they are immediately removed and dried. After this treatment and
exposure to light the shells will have a blood-red luminous appearance
in the dark. The shells thus prepared are used with sulphur and
the phosphide and sulphide of calcium to produce a phosphorescent
composition, as follows: One hundred parts, by weight, of the shells,
prepared as above, are intimately mixed with twenty parts, by weight, of
sulphur. This mixture is placed in a crucible or retort and heated to a
white heat for four or five hours, when it is to be removed and forty
parts more of sulphur, one and one-half parts of calcium phosphide, and
one-half part of chemically pure sulphide of calcium added. The mixture
is then heated for about ninety minutes to an extreme white heat. When
cold, and after exposure to light, this mixture will become luminous.
Instead of these two ignitions, the same object may be in a measure
accomplished by the addition of the full amount of sulphur with the
phosphide and sulphide of calcium and raising it to a white heat but
once. The calcium phosphide is prepared by igniting phosphorus in
connection with newly slaked lime made chemically pure by calcination.
The condition of the shells when the sulphur is added is not material;
but the heat renders them porous and without moisture, so that they will
absorb the salt to as great an extent as possible. Where calcined shells
are mixed with solid salt, the absorbing power of the shells is greatly
diminished by the necessary exposure, and there will be a lack of
uniformity in the saturation. On the contrary, by plunging the red-hot
shells in the saline solution the greatest uniformity is attained.
Instead of using clam shells as the base of my improved composition, I
may use other forms of sea shells--such as oyster shells, etc.
I claim as new:
1. The herein described process of manufacturing phosphorescent
materials, which consists in heating sea shells red-hot, treating them
while heated with a bath of brine, then, after removal from the bath,
mixing sulphur and phosphide and sulphide of calcium therewith, and
finally subjecting the mixture to a white heat, substantially as and for
the purpose described.
2. The described process, which consists in placing clean and red-hot
clam shells in a saturated solution of sea salt, and then drying them,
for the purpose specified.
* * * * *
BOXWOOD AND ITS SUBSTITUTES.
[Footnote: Prize essay written for the International Forestry
Exhibition, Edinburgh.]
Public-domain text, read in full here on John Shaqi.
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