Scientific American Supplement, No. 530, February 27, 1886Various
Science
Scientific American Supplement, No. 530, February 27, 1886
Various
Science -- Periodicals
In the spring of 1883 a Mr. J.B. Thompson, of New Cross, London, patented
a new process of bleaching, the main feature of which consisted in the
use of carbonic acid gas in a closed vessel to decompose the chloride of
lime. The "chemicking" and "souring" operations he performed at one and
the same time. The reactions which took place in his bleaching keir were
stated by the inventor as follows:
Cl.\
1. Ca ) + CO_{2} = CaCO_{3} + Cl_{2}.
OCl./
2. OH_{2} + Cl_{2} = (ClH)_{2} + O.
3. CaCO_{3} + (ClH)_{2} = CaCl_{2} + CO_{2} + H_{2}O.
That is, in 1 chloride of lime and carbonic acid react upon each other,
producing chalk and nascent chlorine; in 2 the nascent chlorine reacts
upon the water of the solution and decomposes it, producing hydrochloric
acid and nascent oxygen, which bleaches; in 3 the hydrochloric acid just
formed reacts upon chalk formed in 1, and produces calcium chloride and
one equivalent of water, and at the same time frees the carbonic acid to
be used again in the process of decomposing the chloride of lime.
When the process was first brought to the notice of the Lancashire
bleachers, it met with an amount of opposition. Some bleaching chemists
declared the process was not patentable, as fully half a century ago
carbonic acid was known to decompose chloride of lime. The patentee's
answer was emphatic, that carbonic acid gas had never been applied in
bleaching before. After some delay one of the largest English cotton
bleachers, Messrs. Ainsworth, Son & Co., Halliwell, Bolton, threw open
their works for a fair test of the Thompson process on a commercial
scale.
The result of trial was so satisfactory that a company was formed to work
the patent. Soon after this the well-known authorities on the oxidation
of cellulose, Messrs. Cross & Bevan and Mr. Mather, the principal partner
in the engineering firm of Mather & Platt, of Salford, Lancashire, joined
the company. For the last twelve months these gentlemen have devoted
considerable attention to improving the original contrivance of Thompson,
and a few weeks since they handed over to Messrs. Ainsworth the machinery
and instructions for what they considered the most complete and best
process of bleaching that has ever been introduced.
Recently a "demonstration" of the "Mather-Thompson" process of bleaching
took place at Halliwell, and to which were invited numerous chemists and
practical bleachers. Having been favored with an invitation, I propose to
lay before your readers a concise report of the proceedings.
Public-domain text, read in full here on John Shaqi.
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