Scientific American Supplement, No. 623, December 10, 1887Various
Science
Scientific American Supplement, No. 623, December 10, 1887
Various
Science -- Periodicals
The cost of producing oxygen at Westminster, under specially expensive
conditions, is high--about 12s. per 1,000 cub. ft. When we consider,
however, that the cost should only embrace attendance, fuel, wear and
tear, and a little lime and soda for the purifiers, that the
consumption of fuel is small, the wear and tear light, and that the
raw material--air--is obtained for nothing, it ought to be possible to
produce the gas for a third or fourth of this amount in most of our
great manufacturing centers, where the price of fuel is but a third of
that demanded in London, and where provision could be made for
economizing the waste heat, which is entirely lost in the Westminster
installation. Moreover, in estimating this cost all the charges are
thrown on the oxygen; were there any means of utilizing the 4,000 cub.
ft. of nitrogen at present blown away as waste for every thousand
cubic feet of oxygen produced, the nitrogen would of course bear its
share of the cost.
The question of the application of the oxygen is one which must be
determined in its manifold bearings mainly by the experiments of
chemists and scientific men engaged in industrial work. Having
ascertained the method by which and the limit of cost within which it
is possible to use oxygen in their work, it can be seen whether by
Brin's process the gas can be obtained within that limit.
Mr. S.R. Ogden, the manager of the corporation gasworks at Blackburn,
has already made interesting experiments on the application of oxygen
in the manufacture of illuminating gas. In order to purify coal gas
from compounds of sulphur, it is passed through purifiers charged with
layers of oxide of iron. When the oxide of iron has absorbed as much
sulphur as it can combine with, it is described as "foul." It is then
discharged and spread out in the open air, when, under the influence
of the atmospheric oxygen, it is rapidly decomposed, the sulphur is
separated out in the free state, and oxide of iron is reformed ready
for use again in the purifiers. This process is called revivification,
and it is repeated until the accumulation of sulphur in the oxide is
so great (45 to 55 per cent.) that it can be profitably sold to the
vitriol maker. Hawkins discovered that by introducing about 3 per
cent. of air into the gas before passing it through the purifiers, the
oxygen of the air introduced set free the sulphur from the iron as
fast as it was absorbed. Thus the process of revivification could be
carried on in the purifiers themselves simultaneously with the
absorption of the sulphur impurities in the gas.
Public-domain text, read in full here on John Shaqi.
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