Scientific American Supplement, No. 648, June 2, 1888.Various
Science
Scientific American Supplement, No. 648, June 2, 1888.
Various
Science -- Periodicals
Here I have an apparatus for heating curling tongs by electricity; here is
a flat iron treated in the same way, and here is a kettle in which the
current is carried to boil water. I travel a good deal, and I always carry
in my traveling bag a battery like this, which is one of Pitkin's
secondary batteries; it is light and extremely convenient. I can strap it
on my shoulder like an opera glass. To this is attached a reading lamp
which I fix in my waistcoat, and to the astonishment of my fellow
travelers, when the shades of evening are beginning to set, I take out the
lamp and put it in operation--so. My reading lamp is thus provided, and it
is fixed in the most convenient position, for the light falls just where
it is wanted, it does not offend the eye, and enables me to read the
smallest print. I have always got with me my own light, perhaps much to
the annoyance of my fellow passengers, and with the electric light
machinery at my own house, I have little or no trouble in recharging the
battery, or keeping it in order. The Pitkin battery is also applied to a
miner's lamp.
EFFECT OF CHLORINE ON THE ELECTRO-MOTIVE FORCE OF A VOLTAIC COUPLE.[6]
By D. G. GORE, F.R.S.
If the electro-motive force of a small voltaic couple of unamalgamated
magnesium and platinum and distilled water is balanced through the coil of
a moderately sensitive galvanometer of about 100 ohms resistance, by means
of that of a small Daniells cell, plus that of a sufficient number of
couples of iron and German silver of a suitable thermo-electric pile (see
Proc. Birm. Phil. Soc., vol. iv., p. 130), the degree of potential being
noted, and sufficiently minute quantities of very dilute chlorine water
are then added in succession to the distilled water, the degree of
electro-motive force of the couple is not affected until a certain
definite proportion of chlorine has been added; the potential then
suddenly commences to increase, and continues to do so with each further
addition within a certain limit. Instead of making the experiment by
adding chlorine water, it may be made by gradually diluting a very weak
aqueous solution of chlorine.
[6] Read before the Royal Society, May 3, 1888.
The minimum proportion of chlorine necessary to cause this sudden change
of electro-motive force is extremely small; in my experiments it has been
one part in 17,000 million parts of water;[7] or less than 1/7000 part of
that required to yield a barely perceptible opacity in ten times the bulk
of a solution of sal-ammoniac by means of nitrate of silver. The quantity
of liquid required for acting upon the couple is small, and it would be
easy to detect the effect of the above proportion or of less than one
ten-thousand millionth part of a grain of chlorine in one tenth of a cubic
centimeter of distilled water by this process. The same kind of action
occurs with other electrolytes, but requires larger proportions of
dissolved substance.
Public-domain text, read in full here on John Shaqi.
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