Scientific American Supplement, No. 711, August 17, 1889Various
History
Scientific American Supplement, No. 711, August 17, 1889
Various
Science -- Periodicals
_Physical Condition._--The brittleness of the substances B and C, the
facility with which they can be reduced to the finest powder, makes a
striking point of difference between allotropic and normal silver. It
is probable that normal silver, precipitated in fine powder and set
aside moist to dry gradually, may cohere into brittle lumps, but these
would be mere aggregations of discontinuous material. With allotropic
silver the case is very different, the particles dry in optical
contact with each other, the surfaces are brilliant, and the material
evidently continuous. That this should be brittle indicates a totally
different state of molecular constitution from that of normal silver.
_Specific Gravities._--The allotropic forms of silver show a lower
specific gravity than that of normal silver.
In determining the specific gravities it was found essential to keep
the sp. gr. bottle after placing the material in it for some hours
under the bell of an air pump. Films of air attach themselves
obstinately to the surfaces, and escape but slowly even in vacuo.
Taken with this precaution, the blue substance, B, gave specific
gravity 9.58, and the yellow substance, C, specific gravity 8.51. The
specific gravity of normal silver, after melting, was found by G. Rose
to be 10.5. That of finely divided silver obtained by precipitation is
stated to be 10.62.[1]
[Footnote 1: Watts' Dict., orig. ed., v. 277.]
I believe these determinations to be exact for the specimens employed.
But the condition of aggregation may not improbably vary somewhat in
different specimens. It seems, however, clear that these forms of
silver have a lower specific gravity than the normal, and this is what
would be expected.
Chestnut Hill, Philadelphia, May, 1889.
--_Amer. Jour. of Science._
* * * * *
TURPENTINE AND ITS PRODUCTS.[1]
[Footnote 1: Read at a meeting of the Liverpool Chemists'
Association.]
By EDWARD DAVIES, F.C.S., F.I.C.
In treating this subject it is necessary to limit it within
comparatively narrow bounds, for bodies of the turpentine class are
exceedingly numerous and not well understood. In this definite class
turpentine means the exudation from various trees of the natural order
Coniferae, consisting of a hydrocarbon, C10 H16, and a resin. The
constitution of the hydrocarbons in turpentine from different sources,
though identical chemically, varies physically, the boiling point
ranging from 156 deg. C. to 163 deg. C., the density from 0.855 to 0.880, and
the action on polarized light from -40.3 to +21.5. They are very
unstable bodies in their molecular constitution, heat, sulphuric acid,
and other reagents modifying their properties. The resins are also
very variable bodies formed probably by oxidation of the hydrocarbons,
and as this oxidation is more or less complete, mixtures are formed
very difficult to separate and study.
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