Scientific American Supplement, No. 711, August 17, 1889Various
History
Scientific American Supplement, No. 711, August 17, 1889
Various
Science -- Periodicals
Turpentine as met with in commerce is mainly derived from _Pinus
maritima_, yielding French turpentine, and _Pinus australis_,
furnishing most of the American turpentine. The latter is obtained
from North and South Carolina, Georgia and Alabama. In Hanbury and
Fluckiger's Pharmacographia there is a full description of the manner
in which the trees are wounded to obtain the turpentine. Besides these
there are Venice turpentine from the larch, _Pinus Larix_, Strassburg
turpentine from _Abies pectinata_, and Canada balsam from _Pinus
balsamea_.
The crude American turpentine is a viscid liquid of about the
consistence of honey, but varying to a soft solid, known as gum, thus,
according to the amount of exposure which it has undergone, it
contains about 10 to 25 per cent. of "spirits," to which the name of
turpentine is commonly given, the rest being resin, or as it is
usually called, rosin.
In Liverpool almost all the spirits of turpentine comes from America,
so that it is almost impossible to get a sample of French.
The terpene from American turpentine is called austraterebenthene. It
possesses dextro-rotatory polarization of +21.5. Its density is 0.864.
Boiling point 156 deg. C.
In taking the boiling point of a commercial sample of spirits it is
necessary to wait until the thermometer becomes steady. Not more than
5 per cent. should pass over before this takes place, and then there
is not more than two or three degrees of rise until almost all is
distilled over.
The liquids of lower boiling point do not appear to have been much
studied. In French spirits they seem to be of the same composition as
the main product, but with more action on polarized light.
French spirits of turpentine is mainly composed of terebenthene. The
boiling point and sp. gr. are the same as those of the austraterebenthene,
but the polarization is left handed and amounts to -40.5.
Isomeric modifications. Heated to 300 deg. C. in a sealed tube for two
hours, it becomes an isomeric compound, boiling at 175 deg. C., while the
density is lowered, being only 0.8586 at 0 deg. C. The rotatory power is
only -9 deg.. It oxidizes much more rapidly. It is called isoterebenthene
and has a smell of essential oil of lemons.
By the action of a small quantity of sulphuric acid, among other
products terebene is formed. It has the same boiling point and sp. gr.
as terebenthene, but is without action on polarized light.
Austraterebenthene forms similar if not identical bodies.
Polymers. One part of boron fluoride BF3 instantly converts 160
parts of terebenthene into polymers boiling above 300 deg. C., and
optically inactive. H2 SO4 does the same on heating and forms
diterebene C20 H32.
Terchloride of antimony does the same, and also produces tetraterebene
C40H64, a solid brittle compound formed by the union of four
molecules of C10 H16. It does not boil below 350 deg. C. and
decomposes on heating.
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